Cu UPD at Pt(100) and stepped faces Pt(610), Pt(410) of platinum single crystal electrodes


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The processes of adsorption/desorption of copper adatoms on the basal Pt(100) face and stepped Pt(610), Pt(410) surfaces have been studied in perchloric acid solution by cyclic voltammetry. It has been shown that the positions of the Cu stripping peaks are determined by perfection of the adlayer. The “island” model is suggested to describe electrochemical behavior of the Pt(hkl)+Cuad system. Obtained results are important for target modification of shape-controlled nanoparticles that are used in electrocatalysis.

Sobre autores

E. Molodkina

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: danilov@phyche.ac.ru
Rússia, Moscow

A. Danilov

Frumkin Institute of Physical Chemistry and Electrochemistry

Autor responsável pela correspondência
Email: danilov@phyche.ac.ru
Rússia, Moscow

J. Feliu

Institute of Electrochemistry

Email: danilov@phyche.ac.ru
Espanha, Alicante

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