The Electric Conductivity of Poly- and Singlecrystaline Y2O3 in Oxidative Atmosphere


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Abstract

Comparative impedance measurements of electric conductivity of nominally undoped yttria are carried out for samples with sharply differing morphologies, namely, single crystals and porous ceramics (with a density of 67%) over a 980–350°С temperature range in air atmosphere of different humidity (рН2О= 40–3000 Pa). Dilatometric analysis of possible structure changes is carried out. The effects of uncontrolled impurities on the yttria defect structure are analyzed.

About the authors

A. I. Kovrova

Institute of High-Temperature Electrochemistry, Ural Division

Author for correspondence.
Email: kovrova@ihte.uran.ru
Russian Federation, Yekaterinburg, 620137

V. P. Gorelov

Institute of High-Temperature Electrochemistry, Ural Division

Email: kovrova@ihte.uran.ru
Russian Federation, Yekaterinburg, 620137

A. V. Kuz’min

Institute of High-Temperature Electrochemistry, Ural Division; Ural Federal University named after the first President of Russia B.N. Yeltsin

Email: kovrova@ihte.uran.ru
Russian Federation, Yekaterinburg, 620137; Yekaterinburg, 620002

B. A.-T. Melekh

Ioffe Physicotechnical Institute

Email: kovrova@ihte.uran.ru
Russian Federation, St. Petersburg, 194021


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