Email this article Electroactive Composite Pd–Polypyrrole and Its Catalytic Properties in the Reaction of Styryl Bromide Cyanation
- Authors: Nikitin O.M.1, Magdesieva T.V.1, Polyakova O.V.1, Sazonov P.K.1, Gor’kov K.V.2, Zolotukhina E.V.2, Vorotyntsev M.A.1,2,3,4
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Affiliations:
- Moscow State University, Faculty of Chemistry
- Institute of Chemical Physics
- Mendeleeev University of Chemical Technology of Russia
- ICMUB, UMR 6302 CNRS
- Issue: Vol 54, No 7 (2018)
- Pages: 608-611
- Section: Short Communications
- URL: https://journals.rcsi.science/1023-1935/article/view/189436
- DOI: https://doi.org/10.1134/S1023193518070066
- ID: 189436
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Abstract
A composite material in the form of powder is synthesized by a redox reaction in mixed aqueous solution of Pd(NH3)4Cl2 + pyrrole. The composite consists of polypyrrole globules with palladium nanoparticles uniformly distributed inside the latter. Being applied as a film on the electrode surface, both components of this material exhibit redox activity. Palladium particles inside the composite exhibit catalytic properties in cyanation of styryl bromides, a reaction widely used in fine organic synthesis.
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About the authors
O. M. Nikitin
Moscow State University, Faculty of Chemistry
Email: tvm@org.chem.msu.ru
Russian Federation, Moscow, 119992
T. V. Magdesieva
Moscow State University, Faculty of Chemistry
Author for correspondence.
Email: tvm@org.chem.msu.ru
Russian Federation, Moscow, 119992
O. V. Polyakova
Moscow State University, Faculty of Chemistry
Email: tvm@org.chem.msu.ru
Russian Federation, Moscow, 119992
P. K. Sazonov
Moscow State University, Faculty of Chemistry
Email: tvm@org.chem.msu.ru
Russian Federation, Moscow, 119992
K. V. Gor’kov
Institute of Chemical Physics
Email: tvm@org.chem.msu.ru
Russian Federation, Chernogolovka, Moscow oblast’, 142432
E. V. Zolotukhina
Institute of Chemical Physics
Email: tvm@org.chem.msu.ru
Russian Federation, Chernogolovka, Moscow oblast’, 142432
M. A. Vorotyntsev
Moscow State University, Faculty of Chemistry; Institute of Chemical Physics; Mendeleeev University of Chemical Technology of Russia; ICMUB, UMR 6302 CNRS
Email: tvm@org.chem.msu.ru
Russian Federation, Moscow, 119992; Chernogolovka, Moscow oblast’, 142432; Moscow, 125047; Dijon
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