Carbon nanofiber paper cathode modification for higher performance of phosphoric acid fuel cells on polybenzimidazole membrane
- Authors: Skupov K.M.1, Ponomarev I.I.1, Razorenov D.Y.1, Zhigalina V.G.2,3, Zhigalina O.M.2, Ponomarev I.I.1, Volkova Y.A.1, Volfkovich Y.M.4, Sosenkin V.E.4
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Affiliations:
- Nesmeyanov Institute of Organoelement Compounds
- Shubnikov Institute of Crystallography
- National Research Center “Kurchatov Institute”
- Frumkin Institute of Physical Chemistry and Electrochemistry of Federal Scientific Research Centre “Crystallography and Photonics” of Russian Academy of Sciences
- Issue: Vol 53, No 7 (2017)
- Pages: 728-733
- Section: Article
- URL: https://journals.rcsi.science/1023-1935/article/view/188868
- DOI: https://doi.org/10.1134/S1023193517070114
- ID: 188868
Cite item
Abstract
Entire carbon nanofiber mats (carbon nanofiber paper) based on polyacrylonitrile pyropolymer composite were prepared by the preliminary oxidation (stabilization) of the initial polymer at 250–350°C in air and following pyrolysis at 800–1200°C under vacuum. The mats were tested as cathodes in a fuel cell on polybenzimidazole membrane. Properties of the pyropolymers which were obtained by polymer carbonization could be significantly changed by the addition of specific additives to polyacrylonitrile and also by changing thermal treatment. Particularly, the addition of Ketjen Black® or Vulcan® XC72 carbon blacks and polyvinyl pyrrolidone during electrospinning step resulted in increase of material electrical conductivity and inner porosity, which is important for improving fuel cell performance. Depending on oxidation and pyrolysis temperature, the physical properties of platinated carbon nanofiber paper and the efficiency of a fuel cell on polybenzimidazole membrane significantly change.
About the authors
K. M. Skupov
Nesmeyanov Institute of Organoelement Compounds
Author for correspondence.
Email: kskupov@gmail.com
Russian Federation, Moscow, 119991
I. I. Ponomarev
Nesmeyanov Institute of Organoelement Compounds
Email: kskupov@gmail.com
Russian Federation, Moscow, 119991
D. Yu. Razorenov
Nesmeyanov Institute of Organoelement Compounds
Email: kskupov@gmail.com
Russian Federation, Moscow, 119991
V. G. Zhigalina
Shubnikov Institute of Crystallography; National Research Center “Kurchatov Institute”
Email: kskupov@gmail.com
Russian Federation, Moscow, 119333; Moscow, 123182
O. M. Zhigalina
Shubnikov Institute of Crystallography
Email: kskupov@gmail.com
Russian Federation, Moscow, 119333
Iv. I. Ponomarev
Nesmeyanov Institute of Organoelement Compounds
Email: kskupov@gmail.com
Russian Federation, Moscow, 119991
Yu. A. Volkova
Nesmeyanov Institute of Organoelement Compounds
Email: kskupov@gmail.com
Russian Federation, Moscow, 119991
Yu. M. Volfkovich
Frumkin Institute of Physical Chemistry and Electrochemistry of Federal Scientific Research Centre “Crystallography and Photonics” of Russian Academy of Sciences
Email: kskupov@gmail.com
Russian Federation, Moscow, 119071
V. E. Sosenkin
Frumkin Institute of Physical Chemistry and Electrochemistry of Federal Scientific Research Centre “Crystallography and Photonics” of Russian Academy of Sciences
Email: kskupov@gmail.com
Russian Federation, Moscow, 119071