Electroless deposition and properties of Co–Re–B alloys
- Authors: Krutskikh V.M.1, Drovosekov A.B.1, Gamburg Y.D.1, Aliev A.D.1, Lyakhov B.F.1, Martynenko V.M.2, Shul’ga Y.M.2
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Affiliations:
- Frumkin Institute of Physical Chemistry and Electrochemistry
- Institute of Problems of Chemical Physics
- Issue: Vol 52, No 2 (2016)
- Pages: 106-114
- Section: Article
- URL: https://journals.rcsi.science/1023-1935/article/view/187713
- DOI: https://doi.org/10.1134/S1023193516020075
- ID: 187713
Cite item
Abstract
The data on the mechanism of electroless (catalytic) deposition of Co–Re–B coatings are obtained by determining the donor capacitance of dimethylamine borane (DMAB) (CH3)2HN · BH3 reductant and the oxidation level of its hydride hydrogen. From the results of the study of isotopic composition of evolved hydrogen, it is concluded that the oxidation level of DMAB hydride hydrogen depends on the catalytic activity of the alloy. The alloys containing up to 46 at % rhenium were produced by the electroless deposition.
About the authors
V. M. Krutskikh
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: gamb@list.ru
Russian Federation, Leninskii pr. 31, Moscow, 119071
A. B. Drovosekov
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: gamb@list.ru
Russian Federation, Leninskii pr. 31, Moscow, 119071
Yu. D. Gamburg
Frumkin Institute of Physical Chemistry and Electrochemistry
Author for correspondence.
Email: gamb@list.ru
Russian Federation, Leninskii pr. 31, Moscow, 119071
A. D. Aliev
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: gamb@list.ru
Russian Federation, Leninskii pr. 31, Moscow, 119071
B. F. Lyakhov
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: gamb@list.ru
Russian Federation, Leninskii pr. 31, Moscow, 119071
V. M. Martynenko
Institute of Problems of Chemical Physics
Email: gamb@list.ru
Russian Federation, pr. Akad. Semenova 1, Chernogolovka, Moscow oblast’, 142432
Yu. M. Shul’ga
Institute of Problems of Chemical Physics
Email: gamb@list.ru
Russian Federation, pr. Akad. Semenova 1, Chernogolovka, Moscow oblast’, 142432