Effect of Binder on the Properties of MWW Zeolite Catalysts in Benzene Alkylation with Propylene
- Авторы: Gerzeliev I.M.1, Zhmylev V.P.1, Khusaimova D.O.1, Shkuropatov A.V.2, Knyazeva E.E.1,2, Ponomareva O.A.1,2, Ivanova I.I.1,2, Maksimov A.L.1
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Учреждения:
- Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
- Faculty of Chemistry, Moscow State University
- Выпуск: Том 59, № 7 (2019)
- Страницы: 695-700
- Раздел: Article
- URL: https://journals.rcsi.science/0965-5441/article/view/180939
- DOI: https://doi.org/10.1134/S0965544119070041
- ID: 180939
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Аннотация
The effect of the nature of the binding component (Al2O3, SiO2, kaolin) on the physicochemical and catalytic properties of catalysts based on a hierarchical zeolite of the MWW framework type in benzene alkylation with propylene has been studied. The best results have been obtained using Al(OH)3 as an Al2O3 precursor. This precursor does not have an adverse effect on the acidic properties of the catalyst and thereby provides an increase in the yield of the desired product, i.e., cumene. The addition of kaolin to this catalyst does not affect the strength characteristics; however, the presence of this binder leads to a decrease in the number of acid sites in the sample.
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I. Gerzeliev
Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
Автор, ответственный за переписку.
Email: gerzeliev@ips.ac.ru
Россия, Moscow, 119991
V. Zhmylev
Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
Email: gerzeliev@ips.ac.ru
Россия, Moscow, 119991
D. Khusaimova
Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
Email: gerzeliev@ips.ac.ru
Россия, Moscow, 119991
A. Shkuropatov
Faculty of Chemistry, Moscow State University
Email: gerzeliev@ips.ac.ru
Россия, Moscow, 119991
E. Knyazeva
Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences; Faculty of Chemistry, Moscow State University
Email: gerzeliev@ips.ac.ru
Россия, Moscow, 119991; Moscow, 119991
O. Ponomareva
Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences; Faculty of Chemistry, Moscow State University
Email: gerzeliev@ips.ac.ru
Россия, Moscow, 119991; Moscow, 119991
I. Ivanova
Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences; Faculty of Chemistry, Moscow State University
Email: gerzeliev@ips.ac.ru
Россия, Moscow, 119991; Moscow, 119991
A. Maksimov
Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
Email: gerzeliev@ips.ac.ru
Россия, Moscow, 119991
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