Oligomerization of Unsaturated Compounds in the Presence of Amorphous Mesoporous Aluminosilicates


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High activity and selectivity of the samples of ASM amorphous mesoporous aluminosilicates in the synthesis of practically important oligomers of various unsaturated compounds (C5–C16 linear α-olefins, cyclooctene, norbornene, and α-methylstyrene) is found. The oligomerization products obtained in the presence of ASM have a broader molecular weight distribution in comparison with the oligomers synthesized over the H-Beta zeolite. The mesoporous structure of the ASM aluminosilicate provides the preparation of dimers of cyclooctene with high selectivity without cycle opening.

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S. Bubennov

Institute of Petroleum Chemistry and Catalysis, Ufa Federal Research Center, Russian Academy of Sciences

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Email: bubennov@list.ru
俄罗斯联邦, Ufa, Republic of Bashkortostan, 450075

N. Grigor’eva

Institute of Petroleum Chemistry and Catalysis, Ufa Federal Research Center, Russian Academy of Sciences

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Email: ngg-ink@mail.ru
俄罗斯联邦, Ufa, Republic of Bashkortostan, 450075

D. Serebrennikov

Institute of Petroleum Chemistry and Catalysis, Ufa Federal Research Center, Russian Academy of Sciences

Email: ngg-ink@mail.ru
俄罗斯联邦, Ufa, Republic of Bashkortostan, 450075

M. Agliullin

Institute of Petroleum Chemistry and Catalysis, Ufa Federal Research Center, Russian Academy of Sciences

Email: ngg-ink@mail.ru
俄罗斯联邦, Ufa, Republic of Bashkortostan, 450075

B. Kutepov

Institute of Petroleum Chemistry and Catalysis, Ufa Federal Research Center, Russian Academy of Sciences

Email: ngg-ink@mail.ru
俄罗斯联邦, Ufa, Republic of Bashkortostan, 450075

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