Oligomerization of Unsaturated Compounds in the Presence of Amorphous Mesoporous Aluminosilicates
- 作者: Bubennov S.V.1, Grigor’eva N.G.1, Serebrennikov D.V.1, Agliullin M.R.1, Kutepov B.I.1
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隶属关系:
- Institute of Petroleum Chemistry and Catalysis, Ufa Federal Research Center, Russian Academy of Sciences
- 期: 卷 59, 编号 7 (2019)
- 页面: 682-690
- 栏目: Article
- URL: https://journals.rcsi.science/0965-5441/article/view/180934
- DOI: https://doi.org/10.1134/S096554411907003X
- ID: 180934
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详细
High activity and selectivity of the samples of ASM amorphous mesoporous aluminosilicates in the synthesis of practically important oligomers of various unsaturated compounds (C5–C16 linear α-olefins, cyclooctene, norbornene, and α-methylstyrene) is found. The oligomerization products obtained in the presence of ASM have a broader molecular weight distribution in comparison with the oligomers synthesized over the H-Beta zeolite. The mesoporous structure of the ASM aluminosilicate provides the preparation of dimers of cyclooctene with high selectivity without cycle opening.
作者简介
S. Bubennov
Institute of Petroleum Chemistry and Catalysis, Ufa Federal Research Center, Russian Academy of Sciences
编辑信件的主要联系方式.
Email: bubennov@list.ru
俄罗斯联邦,
Ufa, Republic of Bashkortostan, 450075
N. Grigor’eva
Institute of Petroleum Chemistry and Catalysis, Ufa Federal Research Center, Russian Academy of Sciences
编辑信件的主要联系方式.
Email: ngg-ink@mail.ru
俄罗斯联邦,
Ufa, Republic of Bashkortostan, 450075
D. Serebrennikov
Institute of Petroleum Chemistry and Catalysis, Ufa Federal Research Center, Russian Academy of Sciences
Email: ngg-ink@mail.ru
俄罗斯联邦,
Ufa, Republic of Bashkortostan, 450075
M. Agliullin
Institute of Petroleum Chemistry and Catalysis, Ufa Federal Research Center, Russian Academy of Sciences
Email: ngg-ink@mail.ru
俄罗斯联邦,
Ufa, Republic of Bashkortostan, 450075
B. Kutepov
Institute of Petroleum Chemistry and Catalysis, Ufa Federal Research Center, Russian Academy of Sciences
Email: ngg-ink@mail.ru
俄罗斯联邦,
Ufa, Republic of Bashkortostan, 450075
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