Interaction of 2-Monosubstituted 1,3-Dioxolanes with Aluminacyclopentanes


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Resumo

The interaction of 2-monosubstituted 1,3-dioxolanes with 3-hexyl-1-ethylaluminacyclopentane leads to the cleavage of the Al–C bond of the metallocycle and the formation of ethylene glycol monoethers after hydrolysis of the resulting reaction mixture. Catalytic amounts of ZrCl4 or Ni(acac)2 activate the process. The reaction of 2-monosubstituted 1,3-dioxolanes with 1-ethyl-3-naphthylaluminacyclopentane yields the product of cleavage of the exocyclic Al–Et bond of aluminacyclopentane.

Sobre autores

T. Dekhtyar’

Bashkir State University, Sterlitamak Branch

Autor responsável pela correspondência
Email: dekhtyartf@mail.ru
Rússia, Sterlitamak, Bashkortostan, 453103

O. Vostrikova

Ufa State Petroleum Technological University

Email: dekhtyartf@mail.ru
Rússia, Ufa, Bashkortostan, 450062

S. Zlotskii

Ufa State Petroleum Technological University

Email: dekhtyartf@mail.ru
Rússia, Ufa, Bashkortostan, 450062

A. Bogomazova

Bashkir State University, Sterlitamak Branch

Email: dekhtyartf@mail.ru
Rússia, Sterlitamak, Bashkortostan, 453103

N. Mikhailova

Ufa State Petroleum Technological University

Email: dekhtyartf@mail.ru
Rússia, Ufa, Bashkortostan, 450062

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