Interaction of 2-Monosubstituted 1,3-Dioxolanes with Aluminacyclopentanes
- Autores: Dekhtyar’ T.F.1, Vostrikova O.S.2, Zlotskii S.S.2, Bogomazova A.A.1, Mikhailova N.N.2
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Afiliações:
- Bashkir State University, Sterlitamak Branch
- Ufa State Petroleum Technological University
- Edição: Volume 59, Nº 6 (2019)
- Páginas: 650-655
- Seção: Article
- URL: https://journals.rcsi.science/0965-5441/article/view/180923
- DOI: https://doi.org/10.1134/S0965544119060082
- ID: 180923
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Resumo
The interaction of 2-monosubstituted 1,3-dioxolanes with 3-hexyl-1-ethylaluminacyclopentane leads to the cleavage of the Al–C bond of the metallocycle and the formation of ethylene glycol monoethers after hydrolysis of the resulting reaction mixture. Catalytic amounts of ZrCl4 or Ni(acac)2 activate the process. The reaction of 2-monosubstituted 1,3-dioxolanes with 1-ethyl-3-naphthylaluminacyclopentane yields the product of cleavage of the exocyclic Al–Et bond of aluminacyclopentane.
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Sobre autores
T. Dekhtyar’
Bashkir State University, Sterlitamak Branch
Autor responsável pela correspondência
Email: dekhtyartf@mail.ru
Rússia, Sterlitamak, Bashkortostan, 453103
O. Vostrikova
Ufa State Petroleum Technological University
Email: dekhtyartf@mail.ru
Rússia, Ufa, Bashkortostan, 450062
S. Zlotskii
Ufa State Petroleum Technological University
Email: dekhtyartf@mail.ru
Rússia, Ufa, Bashkortostan, 450062
A. Bogomazova
Bashkir State University, Sterlitamak Branch
Email: dekhtyartf@mail.ru
Rússia, Sterlitamak, Bashkortostan, 453103
N. Mikhailova
Ufa State Petroleum Technological University
Email: dekhtyartf@mail.ru
Rússia, Ufa, Bashkortostan, 450062
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