Measurement of Adsorption of Methane at High Pressures for Alternative Energy Systems


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Abstract

A technique for the measurement of the equilibrium absolute adsorption of gases, in particular, of natural gas (methane), at pressures up to 10 MPa, is proposed. A plant for use in performing the measurements by means of a volumetric method is described. Estimators of the measurement errors are presented. Adsorption isotherms of methane by AU-1Sh miroporous carbon matter in the range of pressures 10–7–10 MPa and temperatures in the range 178–360 K are obtained by means of the proposed technique.

About the authors

A. A. Fomkin

Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences (IFKhE RAN)

Email: shkolin@bk.ru
Russian Federation, Moscow

A. V. Shkolin

Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences (IFKhE RAN)

Author for correspondence.
Email: shkolin@bk.ru
Russian Federation, Moscow

I. E. Men’shchikov

Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences (IFKhE RAN)

Email: shkolin@bk.ru
Russian Federation, Moscow

A. L. Pulin

Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences (IFKhE RAN)

Email: shkolin@bk.ru
Russian Federation, Moscow

A. A. Pribylov

Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences (IFKhE RAN)

Email: shkolin@bk.ru
Russian Federation, Moscow

I. A. Smirnov

Institute of Medical and Biological Problems, Russian Academy of Sciences

Email: shkolin@bk.ru
Russian Federation, Moscow


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