Ammonia Synthesis and Decomposition with Ru Supported Catalysts
- Авторлар: Shlyapin D.1, Borisov V.1, Temerev V.1, Iost K.1, Fedorova Z.2, Snytnikov P.2
-
Мекемелер:
- Center of New Chemical Technologies BIC, Boreskov Institute of Catalysis
- Boreskov Institute of Catalysis
- Шығарылым: Том 64, № 6 (2023)
- Беттер: 761-772
- Бөлім: Articles
- URL: https://journals.rcsi.science/0453-8811/article/view/231825
- DOI: https://doi.org/10.31857/S0453881123060151
- EDN: https://elibrary.ru/KWYRGM
- ID: 231825
Дәйексөз келтіру
Аннотация
An analytical equation for the rate of formation/consumption of nitrogen in the reversible reaction N2 + + 3H2 ↔ 2NH3 was obtained on the base of the analysis of the catalytic properties of 4%Ru–13.6%Cs/Sibunit and 4%Ru–5.4%Ba–7.9%Cs/Sibunit in the processes of ammonia decomposition (105 Pa; 350–470°C) and synthesis ammonia (6×105–5×106 Pa; 400–430°C). This equation allows one to describe correctly the dependence of the chemical reaction rate on the partial pressures of the components of the reaction mixtures for both forward and reverse reactions. The approach used to obtain the kinetic equation is based on the assumption that the adsorption sites on the ruthenium surface are initially filled with hydrogen and then replaced by nitrogen during competitive interaction. The values of the equilibrium constants and apparent activation energies for the synthesis and decomposition of ammonia on the 4%Ru–13.6%Cs/Sibunit and 4%Ru–5.4%Ba–7.9%Cs/Sibunit was found by using the proposed kinetic equation. The data are in good agreement with the ones presented in the literature.
Авторлар туралы
D. Shlyapin
Center of New Chemical Technologies BIC, Boreskov Institute of Catalysis
Email: borisovtiger86@mail.ru
Russia, 644040, Omsk
V. Borisov
Center of New Chemical Technologies BIC, Boreskov Institute of Catalysis
Хат алмасуға жауапты Автор.
Email: borisovtiger86@mail.ru
Russia, 644040, Omsk
V. Temerev
Center of New Chemical Technologies BIC, Boreskov Institute of Catalysis
Email: borisovtiger86@mail.ru
Russia, 644040, Omsk
K. Iost
Center of New Chemical Technologies BIC, Boreskov Institute of Catalysis
Email: borisovtiger86@mail.ru
Russia, 644040, Omsk
Z. Fedorova
Boreskov Institute of Catalysis
Email: borisovtiger86@mail.ru
Russia, 630090, Novosibirsk
P. Snytnikov
Boreskov Institute of Catalysis
Email: borisovtiger86@mail.ru
Russia, 630090, Novosibirsk
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