Fluorescent ratiometric thermometers based on dyads of tetraphenyl porphyrin and zinc-metallated tetraphenyl porphyrin

A. V. Povolotskiy; Поволоцкий А. В.; O. S. Smirnova; Смирнова О. С.; D. A. Soldatova; Солдатова Д. А.; D. A. Lukyanov; Лукьянов Д. А.

doi:10.31857/S0367676523702824

Fluorescent ratiometric thermometers based on dyads of tetraphenyl porphyrin and zinc-metallated tetraphenyl porphyrin

作者: Povolotskiy A.¹, Smirnova O.¹, Soldatova D.¹, Lukyanov D.¹
隶属关系:
1. Saint-Petersburg State University
期: 卷 87, 编号 11 (2023)
页面: 1631-1636
栏目: Articles
URL: https://journals.rcsi.science/0367-6765/article/view/232503
DOI: https://doi.org/10.31857/S0367676523702824
EDN: https://elibrary.ru/FFIAPS
ID: 232503

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详细

Porphyrins and their derivatives are known for their ability to emit two fluorescence bands. We presented the results of the investigation of the intensity ratio dependence for these bands on temperature in the range of 25–75°C for non-metaled and metal-plated with zinc porphyrins, as well as porphyrin dyads in solutions of 1,2-dichloroethane. A comparative analysis of thermometric parameters of these molecules was carried out.

关键词

porphyrin, porphyrin dyad, fluorescent thermometer, ratiometric thermometry, fluorescence, relative thermal sensitivity

作者简介

A. Povolotskiy

Saint-Petersburg State University

编辑信件的主要联系方式.
Email: alexey.povolotskiy@spbu.ru
Russia, 198504, Saint-Petersburg

O. Smirnova

Saint-Petersburg State University

Email: alexey.povolotskiy@spbu.ru
Russia, 198504, Saint-Petersburg

D. Soldatova

Saint-Petersburg State University

Email: alexey.povolotskiy@spbu.ru
Russia, 198504, Saint-Petersburg

D. Lukyanov

Saint-Petersburg State University

Email: alexey.povolotskiy@spbu.ru
Russia, 198504, Saint-Petersburg

参考

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