Features of the crystal structure of 2D honeycomb frustrated magnet Li 2 Ni 2 TeO 6

A. E. Susloparova; Суслопарова А. Е.; N. S. Fokin; Фокин Н. С.; A. I. Kurbakov; Курбаков А. И.

doi:10.31857/S0367676523702733

Features of the crystal structure of 2D honeycomb frustrated magnet Li₂Ni₂TeO₆

作者: Susloparova A.¹, Fokin N.¹, Kurbakov A.¹
隶属关系:
1. Konstantinov Petersburg Nuclear Physics Institute, National Research Center “Kurchatov Institute”
期: 卷 87, 编号 11 (2023)
页面: 1574-1579
栏目: Articles
URL: https://journals.rcsi.science/0367-6765/article/view/232481
DOI: https://doi.org/10.31857/S0367676523702733
EDN: https://elibrary.ru/EIIJKT
ID: 232481

如何引用文章

全文:

开放存取

##reader.subscriptionAccessGranted##
受限制的访问

订阅存取

详细
作者简介
参考
补充文件
统计

详细

Using neutron powder diffraction at a temperature of 35 K, slightly above the Neel temperature, the features of the crystal structure of two samples of layered honeycomb oxides of the same stoichiometric composition Li₂Ni₂TeO₆ synthesized from precursors, Na₂Ni₂TeO₆ and K₂Ni₂TeO₆, were determined. They have a similar crystal structure, hexagonal space group P63/mcm, structure type P2, but there is a significant difference in the distances between the layers. Both Li₂Ni₂TeO₆ samples crystallize into the orthorhombic space group Cmca, with minor differences in the unit lattice parameters. If Li₂Ni₂TeO₆ from the potassium precursor is single-phase, then the compound from the sodium precursor contains 16 wt % of an additional phase with the same Li₂Ni₂TeO₆ stoichiometry, but more deformed with monoclinic distortions described by the С2/m space group.

关键词

neutron powder diffraction, full-profile analysis, quasi-two-dimensional oxide, honeycomb crystal structure

参考

Kanyolo G.M., Masese T., Matsubara N. et al. // Chem. Soc. Rev. 2021. V. 50. P. 3990.
Васильев А.Н., Волкова О.С., Зверева А.А., Маркина М.М. Низкоразмерный магнетизм. М.: Физматлит, 2018. 304 с.
Kitaev A. // Ann. Phys. 2006. V. 32. P. 2.
Стрельцов С.В., Хомский Д.И. // УФН. 2017. Т. 187. № 11. С. 1205; Streltsov S.V., Khomskii D.I. // Phys. Usp. 2017. No. 6. P. 1121.
Tokura Y., Kanazawa N. // Chem. Rev. 2021. V. 121. P. 2857.
Bauer A., Pfleiderer C. // Springer Ser. Mater. Sci. 2016. V. 228. P. 1.
Pu Y., Liu Y., Liu D. et al. // Int. J. Hydrogen Energy. 2018. V. 43. P. 17271.
Kadari R., Velchuri R., Sreenu K et al. // Mater. Res. Express. 2016. V. 3. Art. No. 115902.
Evstigneeva M.A., Nalbandyan V.B., Petrenko A.A. et al. // Chem. Mater. 2011. V. 23. P. 1174.
Sau K., Kumar P.P. // J. Phys. Chem. C. 2015. V. 119. P. 18 030.
Masese T., Yoshii K., Yamaguchi Y. et al. // Nature Commun. 2018. V. 9. Art. No. 3823.
Yang Z., Jiang Y., Deng L. et al. // J. Power Sources. 2017. V. 360. P. 319.
Jia Zh., Jiang X., Lin Zh., Xia M. // Dalton Trans. 2018. V. 47. P. 16388.
Kuchugura M.D., Kurbakov A.I., Zvereva E.A. et al. // Dalton Trans. 2019. V. 45. No. 7. P. 17070.
Kurbakov A.I., Korshunov A.N., Podchezertsev S.Y. et al. // Phys. Rev. B. 2017. V. 96. Art. No. 024417.
Stratan M.I., Shukaev I.L., Vasilchikova T.M. et al. // New J. Chem. 2019. V. 43. P. 13545.
Korshunov A., Safiulina I., Kurbakov A. // Phys. Stat. Sol. B. 2020. V. 257. Art. No. 1900232.
Kurbakov A.I., Korshunov A.N., Podchezertsev S.Yu. et al. // J. Alloys Compounds. 2020. V. 820. Art. No. 153 354.
Курбаков А.И., Коршунов А.Н., Пирогов А.Н. и др. // Кристаллография. 2021. Т. 66. № 2. С. 271; Kurbakov A.I., Korshunov A.N., Pirogov A.N. et al. // Crystallography Rep. 2021. V. 66. No. 2. P. 267.
Fouet J.B., Sindzingre P., Lhuillier C. // Eur. Phys. J. B. 2001. V. 20. P. 241.
Li P.H.Y., Bishop R.F., Farnell D.J.J., Campbell C.E. // Phys. Rev. B. 2012. V. 86. Art. No. 144404.
Grundish N.S., Seymour I.D., Henkelman G., Goodenough J.B. // Chem. Mater. 2019. V. 31. P. 9379.
Politaev V.V., Nalbandyan V.B., Petrenko A.A. et al. // J. Solid State Chem. 2010. V. 183. P. 684.
Rodriguez-Carvajal J. // Phys. B. 1993. V. 55. P. 192.
Izumi F., Momma K. // Solid State Phenom. 2007. V. 130. P. 15.
Vasilchikova T., Vasiliev A., Evstigneeva M. et al. // Materials. 2022. V. 15. P. 2563.
Shannon R.D. // Acta Crystallogr. A. 1976. V. 32. P. 751.