The effect of crystallization on the Tb 3+  emission parameters in a solution of a terbium(III) complex with tetra-1,3-diketone calix[ 4 ]arene

D.V. Lapaev; Лапаев Д. В.; V. G. Nikiforov; Никифоров В. Г.; S. N. Sudakova; Судакова С. Н.; S. N. Podyachev; Подъячев С. Н.

doi:10.31857/S0367676523702964

The effect of crystallization on the Tb³⁺ emission parameters in a solution of a terbium(III) complex with tetra-1,3-diketone calix[4]arene

Authors: Lapaev D.¹, Nikiforov V.G.¹, Sudakova S.N.², Podyachev S.N.²
Affiliations:
1. Zavoisky Physical-Technical Institute, Federal Research Center “Kazan Scientific Center of the Russian Academy of Sciences”
2. Arbuzov Institute of Organic and Physical Chemistry, Federal Research Center “Kazan Scientific Center of the Russian Academy of Sciences”
Issue: Vol 87, No 12 (2023)
Pages: 1719-1723
Section: Articles
URL: https://journals.rcsi.science/0367-6765/article/view/232530
DOI: https://doi.org/10.31857/S0367676523702964
EDN: https://elibrary.ru/QTYFNE
ID: 232530

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Abstract
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Abstract

An abrupt lengthening (from 295 to 684 μs) of the luminescence decay time of Tb³⁺ ions in a solution of a terbium(III) complex with tetra-1,3-diketone calix[4]arene in the region of the solution crystallization temperature (212 K) was found. This fact indicates a significant sensitivity of the complex to the structure of the local environment, which can be used both for spectroscopic purposes and for remote monitoring of the phase state of the medium.

Keywords

calix[4]arene, 1,3-diketone, Tb³⁺ ion, terbium(III) complex, temperature sensitivity of luminescence parameters, crystallization

About the authors

D.V. Lapaev

Zavoisky Physical-Technical Institute, Federal Research Center “Kazan Scientific Center of the Russian Academy of Sciences”

Author for correspondence.
Email: d_lapaev@mail.ru
Russia, 420029, Kazan

V. G. Nikiforov

Zavoisky Physical-Technical Institute, Federal Research Center “Kazan Scientific Center of the Russian Academy of Sciences”

Email: d_lapaev@mail.ru
Russia, 420029, Kazan

S. N. Sudakova

Arbuzov Institute of Organic and Physical Chemistry, Federal Research Center “Kazan Scientific Center
of the Russian Academy of Sciences”

Email: d_lapaev@mail.ru
Russia, 420088, Kazan

S. N. Podyachev

Arbuzov Institute of Organic and Physical Chemistry, Federal Research Center “Kazan Scientific Center
of the Russian Academy of Sciences”

Email: d_lapaev@mail.ru
Russia, 420088, Kazan

References

Morohashi N., Iki N. Handbook on the physics and chemistry of rare earth. V. 326. Amsterdam: Elsevier, 2022.
Massi M., Ogden M.I. // Materials. 2017. V. 10. P. 1369.
Chen W., Li M., HuiBo W. et al. // Sci. China Tech. Sci. 2018. V. 61. P. 1265.
Zairov R.R., Dovzhenko A.P., Sapunova A.S. et al. // Sci. Reports. 2020. V. 10. P. 20541.
Edwards N.Y., Schnable D.M., Gearba-Dolocan I.R., Strubhar J.L. // Molecules. 2021. V. 26. P. 87.
Silva Lins I.M., da Silva Fonseca J.D., da Luz L.L. et al. // J. Solid State Chem. 2021. V. 295. P. 121916.
Bünzli J.-C.G. // Coord. Chem. Rev. 2015. V. 293–294. P. 19.
Лапаев Д.В., Никифоров В.Г., Лобков В.С. и др. // Изв. РАН. Сер. физ. 2019. Т. 83. № 12. С. 1635; Lapaev D.V., Nikiforov V.G., Lobkov V.S. et al. // Bull. Russ. Acad. Sci. Phys. 2019. V. 83. No. 12. P. 1475.
Лапаев Д.В., Никифоров В.Г., Лобков В.С. и др. // Опт. и спектроск. 2019. Т. 126. № 1. С. 42; Lapaev D.V., Nikiforov V.G., Lobkov V.S. et al. // Opt. Spectrosc. 2019. V. 126. No. 1. P. 34.
Gajjar J.A., Vekariya R.H., Parekh H.M. // Synth. Commun. 2020. V. 50. P. 2545.
Binnemans K. Handbook on the physics and chemistry of rare earths. V. 35. Amsterdam: Elsevier, 2005. P. 107.
Brito H.F., Malta O.L., Felinto M.C.F.C., Teotonio E.E.S. The chemistry of metal enolates. V. 1. Chap. 3. England: John Wiley & Sons Ltd., 2009. P. 131.
Dalal A., Nehra K., Hooda A. et al. // Inorg. Chim. Acta. 2023. V. 550. P. 121406.
Yuan J., Sueda S., Somazawa R. et al. // Chem. Lett. 2003. V. 32. P. 492.
Zairov R., Shamsutdinova N., Podyachev S. et al. // Tetrahedron. 2016. V. 72. P. 2447.
Podyachev S.N., Sudakova S.N., Gimazet-dinova G.Sh. et al. // New J. Chem. 2017. V. 41. P. 1526.
Podyachev S.N., Gimazetdinova G.Sh., Suda-kova S.N. et al. // Tetrahedron. 2017. V. 73. P. 5397.
Podyachev S.N., Sudakova S.N., Gimazet-dinova G.Sh. et al. // Tetrahedron Lett. 2018. V. 59. P. 2695.
Podyachev S.N., Sudakova S.N., Nagimov R.N. et al. // Dalton. Transact. 2019. V. 48. P. 3930.
Лапаев Д.В., Никифоров В.Г., Сафиуллин Г.М. и др. // Журн. структ. химии 2009. Т. 50. № 4. С. 809; Lapaev D.V., Nikiforov V.G., Safiullin G.M. et al. // J. Struct. Chem. 2009. V. 50. No. 4. P. 775.
Lakowicz J.R. Principles of fluorescence spectroscopy. N.Y.: Kluwer Academic, 1999. 698 p.
Лапаев Д.В., Никифоров В.Г., Лобков В.С. и др. // Изв. РАН. Сер. физ. 2021. Т. 85. № 12. С. 1727; Lapaev D.V., Nikiforov V.G., Lobkov V.S. et al. // Bull. Russ. Acad. Sci. Phys. 2021. V. 85. No. 12. P. 1377.
Hüfner S. Optical spectra of transparent rare earth compounds. New York: Academic, 1978. 237 p.
Latva M., Takalo H., Mukkala V.-M. et al. // J. Luminescence. 1997. V. 75. P. 149.
Richardson F.S. // Chem. Rev. 1982. V. 82. P. 541.