Hydrogenation of the Naphthalene Fractions of Coal Tar from Coal of the Shubarkol Deposit


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The results of studies on the hydrogenation of a naphthalene fraction of coal tar performed to obtain high-grade sulfur-free naphthalene and high-purity benzene for organic syntheses and to increase the yield of naphthalene due to hydrodemethylation of its homologues from the feedstock are presented. It was established that the preliminary ozonization of a mixture of crude coke-chemical benzene and the naphthalene fraction (3 : 1) for 60 min makes it possible to obtain a 95–96% yield of valuable chemical products on a converted raw material basis upon the subsequent high-temperature hydrogenation.

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A. Maloletnev

Moscow Mining Institute NITU MISiS

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俄罗斯联邦, Moscow, 119049

N. Smagulova

Research Institute of New Chemical Technologies and Materials

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哈萨克斯坦, Almaty, 050012

Zh. Kairbekov

Research Institute of New Chemical Technologies and Materials

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哈萨克斯坦, Almaty, 050012

A. Kairbekov

Research Institute of New Chemical Technologies and Materials

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哈萨克斯坦, Almaty, 050012

L. Kudreeva

Research Institute of New Chemical Technologies and Materials

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哈萨克斯坦, Almaty, 050012

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