Composition of oily components in the liquid products of the supercritical fluid extraction of oil shale from the Chim-Loptyugskoe deposit


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Abstract

The compositions of hydrocarbon and heteroorganic compounds in the oily components of the liquefaction products of oil shale sampled from the Chim-Loptyugskoe deposit have been investigated in benzene under supercritical conditions in temperature ranges up to 200, 200–300, and 300–400°C. It has been found that they consisted of normal and branched-chain alkanes, including unsaturated isoprenoids; alkenes, saturated and unsaturated naphthenes; mono-, bi-, tri-, tetra-, and pentacyclic aromatic hydrocarbons; compounds from the thiophene and benzo-, dibenzo-, and naphthobenzothiophene series; and aliphatic esters and ketones.

About the authors

E. Yu. Kovalenko

Institute of Petroleum Chemistry, Siberian Branch

Author for correspondence.
Email: azot@ipc.tsc.ru
Russian Federation, Tomsk, 634055

Ya. Yu. Mel’nikov

National Research Tomsk Polytechnic University

Email: azot@ipc.tsc.ru
Russian Federation, pr. Lenina 30, Tomsk, 634050

R. S. Min

Institute of Petroleum Chemistry, Siberian Branch

Email: azot@ipc.tsc.ru
Russian Federation, Tomsk, 634055

T. A. Sagachenko

Institute of Petroleum Chemistry, Siberian Branch

Email: azot@ipc.tsc.ru
Russian Federation, Tomsk, 634055

Yu. F. Patrakov

Federal Research Centre of Coal and Coal Chemistry, Siberian Branch

Email: azot@ipc.tsc.ru
Russian Federation, Kemerovo, 650065

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