LIQUIDUS TEMPERATURE AND DENSITY OF СsBr–KBr–MoBr 3  MELTS

A. V. Isakov; Исаков А. В.; A. O. Khudorozhkova; Худорожкова А. О.; A. P. Apisarov; Аписаров А. П.; A. A. Chernyshev; Чернышев А. А.; M. V. Laptev; Лаптев М. В.; A. S. Shmygalev; Шмыгалев А. С.

doi:10.31857/S0235010623030039

LIQUIDUS TEMPERATURE AND DENSITY OF СsBr–KBr–MoBr₃ MELTS

Authors: Isakov A.V.¹, Khudorozhkova A.O.¹, Apisarov A.P.¹, Chernyshev .A.¹, Laptev M.V.¹, Shmygalev A.S.¹
Affiliations:
1. Institute of High Temperature Electrochemistry, Ural Branch of RAS
Issue: No 3 (2023)
Pages: 307-315
Section: Articles
URL: https://journals.rcsi.science/0235-0106/article/view/138699
DOI: https://doi.org/10.31857/S0235010623030039
EDN: https://elibrary.ru/PRXWXO
ID: 138699

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Abstract

The melting of 60CsBr–40KBr–MoBr₃ (mol %) melts was investigated by synchronous thermal analysis and analysis of cooling curves. The concentration dependence of the liquidus temperature of CsBr–KBr–MoBr₃ melts was recorded. It was found that increase of the MoBr₃ concentration from 0 to 16 wt % leads to increase in the liquidus temperature from 841 to 951 K. It was shown that increase of the MoBr₃ concentration from 2 to 16 wt % leads to increase in the relative mass loss of CsBr–KBr–MoBr₃ from 3 to 13 wt %. It was found, that MoBr₃ crystallizes from CsBr–KBr–MoBr3 melt as a separate phase by X-ray phase analysis. Investigation of density of 60СsBr–40KBr–MoBr₃ (mol %) melt was performed by hydrostatic weighing method. It was shown, that increase in the concentration of MoBr₃ from 2 to 8 wt % in CsBr–KBr–MoBr₃ melts result in to increase of density. The density of the 60CsBr–40KBr–MoBr₃ (mol %) melt decreases with temperature. It is shown that the density of melts (60 mol % CsBr–40 mol % KBr)–MoBr₃ (0–8 wt %) varies within 2.69–3.20 g/cm³ in the temperature range 871–1071 K.

Keywords

cesium bromide, potassium bromide, molybdenum bromide, liquidus temperature, density, thermal analysis, hydrostatic weighing

References

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