New 5-n-C4H9-C2B9-Carborane Ligand and Its Ruthenium Complexes
- Autores: Zimina A.1, Kolpakova T.1, Anufriev S.2, Zueva E.1, Somov N.1, Sivaev I.2, Grishin I.1
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Afiliações:
- Lobachevskii State University (National Research University), Nizhny Novgorod, Russia
- Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia
- Edição: Volume 49, Nº 6 (2023)
- Páginas: 323-332
- Seção: Articles
- URL: https://journals.rcsi.science/0132-344X/article/view/137279
- DOI: https://doi.org/10.31857/S0132344X22600618
- EDN: https://elibrary.ru/URBOGS
- ID: 137279
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Resumo
The reaction of 9-iodo-ortho-carborane with n-butylmagnesium bromide affords 9-n-butyl-ortho-carborane. The reaction of the latter with alkali in boiling ethanol gives new nido-carborane [5-Bu-7,8-C2B9H11]– (I) containing the n-butyl substituent at the lower rim of the basket. The reaction of compound I with RuCl2(PPh3)(Ph2P(CH2)4PPh2) results in the formation of the corresponding ruthenium(IV) closo complex 3,3-(Ph2P(CH2)4PPh2)-3-H-3-Cl-9-Bu-closo-3,1,2-RuC2B9H10 (II) characterized by 2D NMR spectroscopy. On heating compound II can react with carbon tetrachloride to form the 17-electron complex 3,3-(Ph2P(CH2)4PPh2)-3-Cl-9-Bu-closo-3,1,2-RuC2B9H10 (III). The structure of complex III is solved by X-ray diffraction (XRD) (CIF file CCDC no. 2180761). The electrochemical studies show that complex III undergoes the reversible transition Ru(II) → Ru(III) similarly to the earlier studied ruthenacarboranes.
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Sobre autores
A. Zimina
Lobachevskii State University (National Research University), Nizhny Novgorod, Russia
Email: grishin_i@ichem.unn.ru
Россия, Нижний Новгород
T. Kolpakova
Lobachevskii State University (National Research University), Nizhny Novgorod, Russia
Email: grishin_i@ichem.unn.ru
Россия, Нижний Новгород
S. Anufriev
Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia
Email: grishin_i@ichem.unn.ru
Россия, Москва
E. Zueva
Lobachevskii State University (National Research University), Nizhny Novgorod, Russia
Email: grishin_i@ichem.unn.ru
Россия, Нижний Новгород
N. Somov
Lobachevskii State University (National Research University), Nizhny Novgorod, Russia
Email: grishin_i@ichem.unn.ru
Россия, Нижний Новгород
I. Sivaev
Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia
Email: sivaev@ineos.ac.ru
Россия, Москва
I. Grishin
Lobachevskii State University (National Research University), Nizhny Novgorod, Russia
Autor responsável pela correspondência
Email: grishin_i@ichem.unn.ru
Россия, Нижний Новгород
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