Synthesis, Supramolecular Self-Organization, and Thermal Behavior of the Double 3D Pseudo-Polymer Complex [Au{S2CN(CH2)6}2]4[Ag5Cl9] Comprising the New Type Silver(I) Anion
- Authors: Korneeva E.V.1, Loseva O.V.1, Smolentsev A.I.2, Ivanov A.V.1
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Affiliations:
- Institute of Geology and Nature Management, Far Eastern Branch, Russian Academy of Sciences
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch
- Issue: Vol 50, No 1 (2024)
- Pages: 41-52
- Section: Articles
- URL: https://journals.rcsi.science/0132-344X/article/view/260963
- DOI: https://doi.org/10.31857/S0132344X24010052
- EDN: https://elibrary.ru/OSMKFU
- ID: 260963
Cite item
Abstract
New crystalline pseudo-polymer complex [Au{S2CN(CH2)6}2]4[Ag5Cl9] (I) was prepared by inding gold(III) with silver(I) dithiocarbamate from an AuCl3/2.5 M NaCl solution. Complex I is isolated in a preparative yield and structurally characterized. The X-ray diffraction (XRD) data (CIF file CCDC no. 2205197) show that the isomeric cations [Au{S2CN(CH2)6}2]+ (A : 2B : C) and complicated pentanuclear anion [Ag5Cl9]4– are the main structural units of the compound. The supramolecular self-organization of the ionic structural units in complex I occurs due to multiple secondary interactions Cl···S and Ag···S, hydrogen bonds C–H···Cl, and anagostic interactions C–H···Ag leading to the formation of the 3D pseudo-polymer framework. The thermal behavior of complex I is studied by simultaneous thermal analysis to find that the thermolysis of the double Au(III)—Ag(I) compound is accompanied by the quantitative regeneration of the bound metals under comparatively mild conditions.
About the authors
E. V. Korneeva
Institute of Geology and Nature Management, Far Eastern Branch, Russian Academy of Sciences
Email: alexander.v.ivanov@chemist.com
Russian Federation, Blagoveshchensk
O. V. Loseva
Institute of Geology and Nature Management, Far Eastern Branch, Russian Academy of Sciences
Email: alexander.v.ivanov@chemist.com
Russian Federation, Blagoveshchensk
A. I. Smolentsev
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: alexander.v.ivanov@chemist.com
Russian Federation, Novosibirsk
A. V. Ivanov
Institute of Geology and Nature Management, Far Eastern Branch, Russian Academy of Sciences
Author for correspondence.
Email: alexander.v.ivanov@chemist.com
Russian Federation, Blagoveshchensk
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