Coordination Polymer or Cluster: Zinc Bis(3,5-di-tert-octyl-semiquinolate) with Pyrazine

A. V. Maleeva; Малеева А. В.; O. Yu. Trofimova; Трофимова О. Ю.; T. N. Kocherova; Кочерова Т. Н.; I. A. Yakushev; Якушев И. А.; A. S. Bogomyakov; Богомяков А. С.; A. V. Piskunov; Пискунов А. В.

doi:10.31857/S0132344X23600315

Coordination Polymer or Cluster: Zinc Bis(3,5-di-tert-octyl-semiquinolate) with Pyrazine

Authors: Maleeva A.V.¹, Trofimova O.Y.¹, Kocherova T.N.¹, Yakushev I.A.², Bogomyakov A.S.³, Piskunov A.V.¹
Affiliations:
1. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhny Novgorod, Russia
2. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia
3. International Tomography Center, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
Issue: Vol 49, No 11 (2023)
Pages: 693-705
Section: Articles
URL: https://journals.rcsi.science/0132-344X/article/view/162360
DOI: https://doi.org/10.31857/S0132344X23600315
EDN: https://elibrary.ru/NBZBCX
ID: 162360

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Abstract
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Abstract

New zinc bis-o-semiquinolate complexes based on 3,5-di-tert-octyl-o-benzoquinone bearing the N-donor ligand (pyrazine) coordinated to the metal are synthesized. Two different products can be obtained depending on the synthesis method: coordination polymer (direct oxidation of metallic zinc with o-quinone (CIF file CCDC no. 2250574 (I)) or polynuclear cluster (exchange reaction (CIF file CCDC no. 2250575 (II)). The coordination polymer is linear and free of intermolecular π,π interactions between the aromatic fragments of the adjacent molecules. The magnetochemical study of complexes I and II shows that intramolecular antiferromagnetic exchange interactions between spins of the o-semiquinolate radical centers dominate.

Keywords

redox-active ligand, o-quinones, coordination polymers, zinc, XRD, magnetic susceptibility

References

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