Estimation of the Standard Enthalpy of Formation of Crystalline Alkali Metal Borates

A. A. Tupitsin; Тупицын А. А.; V. A. Bychinskii; Бычинский В. А.; M. V. Shtenberg; Штенберг М. В.; S. V. Fomichev; Фомичев С. В.; O. N. Koroleva; Королева О. Н.

doi:10.31857/S0044457X22601808

Estimation of the Standard Enthalpy of Formation of Crystalline Alkali Metal Borates

作者: Tupitsin A.A.¹^,2, Bychinskii V.A.¹, Shtenberg M.V.², Fomichev S.V.³, Koroleva O.N.²
隶属关系:
1. Vinogradov Institute of Geochemistry, Siberian Branch, Russian Academy of Sciences
2. South Ural Federal Research Center for Mineralogy and Geoecology, Ural Branch, Russian Academy of Sciences
3. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
期: 卷 68, 编号 3 (2023)
页面: 325-332
栏目: ФИЗИЧЕСКИЕ МЕТОДЫ ИССЛЕДОВАНИЯ
URL: https://journals.rcsi.science/0044-457X/article/view/136330
DOI: https://doi.org/10.31857/S0044457X22601808
EDN: https://elibrary.ru/JELGYI
ID: 136330

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详细

A structure–property correlation has been developed, which makes it possible to choose the optimal values of the enthalpy of formation of alkali metal borates, for which, according to the data of various experimental works and reference publications, wide variations are observed. Using this correlation, the enthalpy of formation of unstudied alkali metal borates can be reasonably estimated. It has been found that the contribution of B2O3 to the enthalpy of formation is the same not only for alkali metal borates but also for Ba, Ca, and Pb borates, for whose enthalpy of formation a structure–property correlation has also been established. This suggests the suitability of the obtained correlations for estimating the enthalpy of formation in the borate series, where the value is known only for one member of the series, as well as the possibility of estimating the enthalpy of formation of mixed borates of different metals.

关键词

enthalpy of formation, evaluation of thermodynamic properties, oxide increments

参考

Bernard E., Lothenbach B., Cau-Dit-Coumes C. et al. // Appl. Geochem. 2018. V. 89. P. 229. https://doi.org/10.1016/j.apgeochem.2017.12.005
Chudnenko K.V., Palyanova G.A. // Appl. Geochem. 2016. V. 66. P. 88. https://doi.org/10.1016/j.apgeochem.2015.12.005
Lothenbach B., Kulik D.A., Matschei T. et al. // Cem. Concr. Res. 2019. V. 115. P. 472. https://doi.org/10.1016/j.cemconres.2018.04.018
Zhen-Wu B.Y., Prentice D.P., Ryan J.V. et al. // npj Mater. Degr. 2020. V. 4. № 1. P. 2. https://doi.org/10.1038/s41529-019-0106-1
Bychinsky V., Charykova M., Omara R. // Geochem. 2021. V. 81. № 4. P. 125799. https://doi.org/10.1016/j.chemer.2021.125799
Мухетдинова А.В., Бычинский В.А., Тупицын А.А. и др. // Изв. вузов. Цвет. мет. 2009. № 4. С. 29.
Grushko I.S., Bychinskii V.A., Chudnenko K.V. // JOM. 2021. V. 73. № 10. P. 3000. https://doi.org/10.1007/s11837-021-04820-w
Bykov V.N., Koroleva O.N. // Geochem. Int. 2010. V. 48. № 11. P. 1128. https://doi.org/10.1134/s0016702910110066
Koroleva O.N., Bychinsky V.A., Tupitcyn A.A. // J. Non-Cryst. Solids. 2021. V. 571. P. 121065. https://doi.org/10.1016/j.jnoncrysol.2021.121065
Бычинский В.А., Тупицын А.А., Королева О.Н. и др. // Журн. неорган. химии. 2013. Т. 58. № 7. С. 930.
Гурвич Л.В., Вейц И.В., Медведев В.А. и др. Термодинамические свойства индивидуальных веществ / Под ред. Глушко В.П. Т. III. Кн. 1. М.: Наука, 1981. 472 с. Т. IV. Кн. 1. М.: Наука, 1982. 623 с.
Chase M.W., Davies C.A., Downey J.R. et al. JANAF Thermochemical Tables. Third Edition. Washington, D.C.: Am. Chem. Soc., 1985. Part I. 926 p. Part II. 929 p.
Rollet A.P. // C.R. Acad. Sci. 1936. V. 202. P. 1863.
Morey G.W., Merwing H.E. // J. Am. Chem. Soc. 1936. V. 58. № 11. P. 2248. https://doi.org/10.1021/ja01302a048
Sastry B.S.R., Hummel F.A. // J. Am. Ceram. Soc. 1958. V. 41. № 1. P. 7. https://doi.org/10.1111/j.1151-2916.1958.tb13496.x
Sastry B.S.R., Hummel F.A. // J. Am. Ceram. Soc. 1959. V. 42. № 5. P. 216. https://doi.org/10.1111/j.1151-2916.1959.tb15456.x
Adami L.H., Joe C.J. Heats of formation of four anhydrous sodium borates. Washington: U. S. Dept. of the Interior, Bureau of Mines. 1968. 9 p.
Медведев В.А., Бергман Г.А., Васильев В.П. и др. Термические константы веществ / Под ред. Глушко В.П. Вып. V. М.: ВИНИТИ, 1971. 530 с. Вып. IX. М.: ВИНИТИ, 1979. 574 с. Вып. X. Ч. 1. М.: ВИНИТИ, 1981. 299 с. Вып. X. Ч. 2. М.: ВИНИТИ, 1981. 441 с.
Wang C., Yu H., Liu H., Jin Z. // J. Phase Equilib. 2003. V. 24. № 1. P. 12. https://doi.org/10.1007/s11669-003-0003-7
Jenkins H.D.B. // J. Chem. Thermodyn. 2019. V. 135. P. 278. https://doi.org/10.1016/j.jct.2019.03.013
Jenkins H.D.B. // J. Chem. Thermodyn. 2020. V. 144. P. 106052. https://doi.org/10.1016/j.jct.2020.106052
Еремин О.В., Эпова Е.С., Русаль О.С. и др. // Журн. неорган. химии. 2016. Т. 61. № 8. С. 1053.
Wu T., Moosavi-Khoonsari E., Jung I.-H. // Calphad. 2017. V. 57. P. 107. https://doi.org/10.1016/j.calphad.2017.03.002
Алдабергенов М.К., Балакаева Г.Т. // Журн. физ. химии. 1993. Т. 67. № 3. С. 425.
Королева О.Н., Бычинский В.А., Тупицын А.А. и др. // Журн. неорган. химии. 2015. Т. 60. № 9. С. 1211.
Штенберг М.В., Бычинский В.А., Королева О.Н. и др. // Журн. неорган. химии. 2017. Т. 62. № 11. С. 1470.
Shartsis L., Capps W. // J. Am. Ceram. Soc. 1954. V. 37. № 1. P. 27. https://doi.org/10.1111/j.1151-2916.1954.tb13974.x
Шульц М.М., Борисова Н.В., Ведищева Н.М. и др. // Физ. хим. стекла. 1979. Т. 5. № 1. С. 36.
Joshio T., Takahashi K. // J. Ceram. Soc. Jpn. 1976. V. 84. P. 62.
Колесов В.П., Скуратов С.М., Зайкин И.Д. // Журн. неорган. химии. 1959. Т. 4. № 6. С. 1237.
Grenier G., White D. // J. Phys. Chem. 1957. V. 61. № 12. P. 1681.
Wagman D.D., Evans W.H., Parker V.B. et al. Selected Values of Chemical Thermodynamic Properties. Compounds of Uranium, Protactinium, Thorium, Actinium, and the Alkali Metals. NBS Tech. Note 270-8. Washington: 1981. 149 p.
Yokokawa H. // J. Nat. Chem. Lab. Industry. 1988. V. 83. P. 27.
Knacke O., Kubaschewski O., Hesselmann K. Thermochemical Properties of Inorganic Substances. 2nd Edition. Berlin: Springer-Verlag, 1991. 2412 p.
Kubaschewski O., Alock C.B., Spencer P.J. Material Thermochemistry. N.Y.: Pergamon Press, 1993. 363 p.
Pankratz L.B. Thermodynamic properties of carbides, nitrides, and other selected substances. Washington: U. S. Dep. of the Interior, Bureau of Mines, Bul. 696. 1994. 957 p.
Barin I. Thermochemical data of pure substances. 3th ed. Weinheim: VCH-Verlag, 1996. 1885 p.
Лопатин С.И., Столярова В.Л., Тюрнина Н.Г. и др. // Журн. общ. химии. 2006. Т. 76. № 11. С. 1767. Lopatin S.I., Stolyarova V.L., Tyurnina N.G. et al. // Russ. J. Gen. Chem. 2006. V. 76. № 11. P. 1687.
Guest M.F., Pedley L.B., Norn M. // J. Chem. Thermodyn. 1969. V. 1. P. 345. https://doi.org/10.1016/0021-9614(69)90064-0
Wu K-X., Zhao X-J., Liu Z-H. // J. Chem. Thermodyn. 2018. V. 121. P. 170. https://doi.org/10.1016/j.jct.2018.02.020
Cox J.D., Wagman D.D., Medvedev V.A. CODATA Key Values for Thermodynamics. N.Y.: Hemisphere Publishing Corp., 1989. 271 p.