Synthesis and Electronic Structure of Bimetallic AuFe Nanocomposites

A. Yu. Vasil’kov; Васильков А. Ю.; A. A. Voronova; Воронова А. А.; A. V. Naumkin; Наумкин А. В.; I. E. Butenko; Бутенко И. Е.; Ya. V. Zubavichus; Зубавичус Я. В.

doi:10.31857/S0044457X23600147

Synthesis and Electronic Structure of Bimetallic AuFe Nanocomposites

Authors: Vasil’kov A.Y.¹, Voronova A.A.¹, Naumkin A.V.¹, Butenko I.E.¹, Zubavichus Y.V.²
Affiliations:
1. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
2. SRF SKIF, Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences
Issue: Vol 68, No 7 (2023)
Pages: 885-895
Section: СИНТЕЗ И СВОЙСТВА НЕОРГАНИЧЕСКИХ СОЕДИНЕНИЙ
URL: https://journals.rcsi.science/0044-457X/article/view/136354
DOI: https://doi.org/10.31857/S0044457X23600147
EDN: https://elibrary.ru/RIJQUX
ID: 136354

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Abstract
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Abstract

Au, Fe, and AuFe nanoparticles were obtained by metal vapor synthesis using acetone as the dispersion medium. The composition and electronic structure of the particles were studied by TEM, SEM, XPS, XANES, and EXAFS. The Au and Fe particles with average diameters of 5.3 and 1.8 nm, respectively, were obtained. According to X-ray diagnostic methods, gold was in the main Au0 state, and the Au+ and Au3+ states are present in small amounts while iron existed as mixture of non-stoichiometric oxides with states close to Fe2+ and Fe3+. Bimetallic nanoparticles were solid solutions with a disordered structure and Au–Fe–O and Au–O–Fe bonds. A carbon-containing shell was detected for all types of metal particles. The obtained materials may be promising for the development of improved antimicrobial agents and new methods for treating cancer diseases.

Keywords

nanoparticles, iron, gold, metal vapor synthesis, XPS, EXAFS/XANES

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