IONIC LIQUIDS AS PROMISING FUNCTIONAL MATERIALS FOR MICROEXTRACTION OF STEROID HORMONES

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Prospects for the use of imidazolium ionic liquids (IL) as extractants of sex steroid hormones (estrogens and androgens) in microextraction methods (dispersive liquid-liquid microextraction, DLLME, and magnetic solid-phase microextraction, mSPME) are identified. The key parameters of DLLME using C6MImNTf2 IL, affecting the extraction efficiency, are optimized using the design of experiment method. High degrees of recovery (88–99 %) are achieved. An approach of dynamic IL immobilization on the surface of magnetic nanoparticles (MNPs) for steroid extraction under mSPME conditions is proposed. Two types of MNP pre-coating are studied: hydrophilic based on silica and hydrophobic with oleic acid. The capabilities of C8MImBF4 IL as a MNP surface modifier for efficient steroid extraction are revealed. Optimum conditions provided high degrees of recovery (83–97 %), with the exception of estriol (60 %). The detection limits are 0.26–1.29 ng/mL. Limitations of the method related to partial removal of IL from the surface of NPs are revealed, which reduces the reproducibility of the results for estriol.

作者简介

A. Araslanova

Saint Petersburg State University, Institute of Chemistry

Universitetskii pr. 26, Petrodvorets, Saint Petersburg, Russia

M. Vasilenko

Saint Petersburg State University, Institute of Chemistry

Universitetskii pr. 26, Petrodvorets, Saint Petersburg, Russia

E. Bessonova

Saint Petersburg State University, Institute of Chemistry

Email: Lena_pol@inbox.ru
Universitetskii pr. 26, Petrodvorets, Saint Petersburg, Russia

L. Kartsova

Saint Petersburg State University, Institute of Chemistry

Universitetskii pr. 26, Petrodvorets, Saint Petersburg, Russia

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