The Effect of Redox Electrolyte on the Electrochemical Characteristics of a PEDOT–(Sodium 1,2-Naphthoquinone-4-sulfonate)/WMNT Nanocomposite Electrode

Capa

Citar

Texto integral

Acesso aberto Acesso aberto
Acesso é fechado Acesso está concedido
Acesso é fechado Somente assinantes

Resumo

The methods of cyclic voltammetry, galvanostatic charge–discharge, and electrochemical impedance spectroscopy were used to study the effect of electrolyte redox on the electrochemical characteristics of a composite based on a poly(3,4-ethylenedioxythiophene) (PEDOT) conducting polymer and multiwalled carbon nanotubes (MWCNTs). To form a uniform thin layer of PEDOT on the surface of nanotubes, an enzymatic polymerization of the monomer was used. The electrochemically active compound sodium 1,2‑naphthoquinone-4-sulfonate (NQS) was a dopant in the main PEDOT chain and, at the same time, a component of the electrolyte. The addition of 12.5 mM NQS to the electrolyte increased the specific capacitance of the PEDOT–NQS/MWCNT composite electrode from 390 to 800 F/g at a potential sweep rate of 10 mV/s. In a 1 M H2SO4 + 12.5 mM NQS redox electrolyte, the composite electrode exhibited higher cyclic stability and lower charge transfer resistance compared to 1 M H2SO4. After 1000 cycles of potential scanning in the range from –0.1 to 0.8 V at a rate of 100 mV/s, the specific capacitance of the composite electrode in a solution of 1 M H2SO4 decreased by 8%, and in a solution of 1 M H2SO4 + 12.5 mm NQS increased by approximately 9%.

Sobre autores

G. Shumakovich

Bach Institute of Biochemistry, Federal Research Center “Fundamentals of Biotechnology” of the Russian Academy of Sciences

Email: victoremets@mail.ru
119071, Moscow, Russia

I. Vasilyeva

Bach Institute of Biochemistry, Federal Research Center “Fundamentals of Biotechnology” of the Russian Academy of Sciences

Email: victoremets@mail.ru
119071, Moscow, Russia

V. Emets

Frumkin Institute of Physical Chemistry and Electrochemistry, Academy of Sciences

Email: victoremets@mail.ru
119071, Moscow, Russia

V. Bogdanovskaya

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: bogd@elchem.ac.ru
Moscow, 119071 Russia

A. Kuzov

Frumkin Institute of Physical Chemistry and Electrochemistry, Academy of Sciences

Email: victoremets@mail.ru
119071, Moscow, Russia

V. Andreev

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: elena_pisarevska@bk.ru
Moscow, Russia

O. Morozova

Bach Institute of Biochemistry, Federal Research Center “Fundamentals of Biotechnology” of the Russian Academy of Sciences

Email: victoremets@mail.ru
119071, Moscow, Russia

A. Yaropolov

Bach Institute of Biochemistry, Federal Research Center “Fundamentals of Biotechnology” of the Russian Academy of Sciences

Autor responsável pela correspondência
Email: victoremets@mail.ru
119071, Moscow, Russia

Bibliografia

  1. Sun K., Feng E., Peng H., Ma G. et al. // Electrochimica Acta. 2015. V. 158. № 10. P. 361–367.
  2. Veerasubramani G.K., Krishnamoorthy K., Pazhamalai P., Kim S.J. // Carbon. 2016. V. 105. P. 638–648.
  3. Meng W., Xia Y., Ma C., Du X. // Polymers. 2020. V. 12. № 10. P. 2303.
  4. Wang X., Chandrabose R.S., Chun S.-E., Zhang T. et al. // ACS Appl. Mater. Interfaces. 2015. V. 7. № 36. P. 19978–19985.
  5. Lota G., Fic K., Frackowiak E. // Electrochemistry Communications. 2011. V. 13. № 1. P. 38–41.
  6. Sun S., Rao D., Zhai T., Liu Q. et al. // Advanced Materials. 2020. V. 32. № 43. P. 2005344.
  7. Raja A., Selvakumar K., Swaminathan M., Kang M. // Synthetic Metals. 2021. V. 276. P. 116753.
  8. Senthilkumar S.T., Selvan R.K., Ponpandian N., Melo J.S. et al. // J. Mater. Chem. A. 2013. V. 27. P. 7913–7919.
  9. Kasturi P.R., Harivignesh R., Lee Y.S., Selvan R.K. // J. Physics and Chemistry of Solids. 2020. V. 143. P. 109447.
  10. Han W., Kong L.-B., Liu M.-C., Wang D. et al. // Electrochimica Acta. 2015. V. 186. P. 478–485.
  11. Chun S.-E., Evanko B., Wang X., Vonlanthen D. et al. // Nature Communications. 2015. V. 6. P. 7818.
  12. Chen W., Rakhi R.B., Alshareef H.N. // Nanoscale. 2013. V. 5. № 10. P. 4134–4138.
  13. Vonlanthen D., Lazarev P., See K.A., Wudl F. et al. // Advanced Materials. 2014. V. 26. № 30. P. 5095–5100.
  14. Wang T., Hu S., Wu D., Zhao W. et al. // J. Mater. Chem. A. 2021. V. 9. № 19. P. 11839–11852.
  15. Tian Y., Liu M., Che R., Xue R. et al. // Journal of Power Sources. 2016. V. 324. P. 334–341.
  16. Sakita A.M.P., Ortega P.F.R., Silva G.G., Noce R.D. et al. // Electrochimica Acta. 2021. V. 390. P. 138803.
  17. Wang Q., Nie Y.F., Chen X.Y., Xiao Z.H. et al. // J. Power Sources. 2016. V. 323. P. 8–16.
  18. Sheng L., Fang D., Wang X., Tang J. et al. // Chemical Engineering J. 2020. V. 401. P. 126123.
  19. Nasrin K., Gokulnath S., Karnan M., Subramani K. et al. // Energy Fuels. 2021. V. 35. № 8. P. 6465–6482.
  20. Li Y., Cao R., Song J., Liang L. et al. // Materials Research Bulletin. 2021. V. 139. P. 111249.
  21. Xie H., Zhu Y., Wu Y., Wu Z. et al. // Materials Research Bulletin. 2014. V. 50. P. 303–306.
  22. Otrokhov G.V., Shumakovich G.P., Khlupova M.E., Vasil’eva I.S. et al. // RSC Advanced. 2016. V. 6. P. 60372–60375.
  23. Kanth S., Narayanan P., Betty C.A., Rao R. et al. // J. Applied Polymer Science. 2021. V. 138. № 24. P. e50838.
  24. Skunik-Nuckowska M., Lubera J., Raczka P., Mroziewicz A.A., Dyjak S., Kulesza P.J. // ChemElectroChem. 2022. V. 9. No. 2. P. e202101222.
  25. Groenendaal L., Jonas F., Freitag D., Pielartzik H., Reynolds J.R. // Advanced Materials. 2000. V. 12. № 7. P. 481–494.
  26. Горшина Е.С., Русинова Т.В., Бирюков В.В., Морозова О.В. и др. // Прикл. биохимия и микробиология, 2006. Т. 42. № 6. С. 558–563.
  27. Shumakovich G.P., Kurova V., Vasil’eva I., Pankratov D. et al. // J. Molecular Catalysis B: Enzymatic. 2012. V. 77. P. 105–110.
  28. Vasil'eva I.S., Shumakovich G.P., Khlupova M.E., Vasiliev R.B. et al. // RSC Advances. 2020. V. 10. P. 33010–33017.
  29. Shumakovich G.P., Morozova O.V., Khlupova M.E., Vasil’eva I.S. et al. // RSC Advanced. 2017. V. 7. P. 34192–34196.
  30. Kvarnström C., Neugebauer H., Blomquist S., Ahonen H.J., Kankare J., Ivaska A. // Electrochimica Acta. 1999. V. 44. P. 2739–2750.
  31. Uzuncar S., Ozdogan N., Ak M. //Analytica Chimica Acta. 2021. V. 11728. P. 338664.
  32. Lota K., Khomenko V., Frackowiak E. // J. Phys. Chem. Solids. 2004. V. 65. P. 295–301.

Arquivos suplementares

Arquivos suplementares
Ação
1. JATS XML
2.

Baixar (18KB)
3.

Baixar (67KB)
4.

Baixar (918KB)
5.

Baixar (325KB)
6.

Baixar (87KB)
7.

Baixar (90KB)
8.

Baixar (24KB)
9.

Baixar (36KB)
10.

Baixar (31KB)
11.

Baixar (35KB)
12.

Baixar (59KB)

Declaração de direitos autorais © Г.П. Шумакович, И.С. Васильева, В.В. Емец, В.А. Богдановская, А.В. Кузов, В.Н. Андреев, О.В. Морозова, А.И. Ярополов, 2023

Este site utiliza cookies

Ao continuar usando nosso site, você concorda com o procedimento de cookies que mantêm o site funcionando normalmente.

Informação sobre cookies