Effect of the Porous Structure of a Catalyst on the Rate of Its Deactivation in the Claus Reaction


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The effect produced by the content of different size pores and the diameter of a catalyst grain on the deactivation rate has been estimated based on the experimental data on the conversion of H2S in the Claus reaction. Catalysts with different pore size distributions have been used for analysis. Deactivation has been shown to occur in different fashions for a fine catalyst fraction and catalyst grains. A mathematical model that describes the process of deactivation has been proposed.

Sobre autores

V. Khanaev

Novosibirsk State Technical University

Autor responsável pela correspondência
Email: VMKhanaev@gmail.com
Rússia, pr. Karla Marksa 20, Novosibirsk, 630073

E. Borisova

Boreskov Institute of Catalysis, Siberian Branch

Email: VMKhanaev@gmail.com
Rússia, pr. Akademika Lavrent’eva 5, Novosibirsk, 630090

P. Kalinkin

Boreskov Institute of Catalysis, Siberian Branch

Email: VMKhanaev@gmail.com
Rússia, pr. Akademika Lavrent’eva 5, Novosibirsk, 630090

O. Kovalenko

Boreskov Institute of Catalysis, Siberian Branch

Email: VMKhanaev@gmail.com
Rússia, pr. Akademika Lavrent’eva 5, Novosibirsk, 630090

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