Calculation of Seawater Density

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Resumo

An equation for calculating the density of multicomponent aqueous solutions of electrolytes is proposed and a calculation of the density of seawater is carried out at 20°С. It is established that six salts make the main contribution to the density of the solutions: sodium, magnesium, calcium and potassium chlorides, and sodium sulfate and bicarbonate. The molar volumes of magnesium and calcium chlorides, as well as sodium sulfate and bicarbonate, are determined. Based on these data on molar volumes and the previously found values for sodium and potassium chlorides, we calculate the density of seawater at 20°С. The resulting value is 1023.7 kg/m3, which practically coincides with the value available in the literature of 1023.6 kg/m3, given for 25°С. The applied technique can be used to calculate the density of technological solutions with various salt compositions

Sobre autores

A. Ochkin

D.I. Mendeleev Russian University of Chemical Technology

Email: ochkinav@muctr.ru
Moscow, Russia

N. Kulov

N.S. Kurnakova Institute of General and Inorganic Chemistry

Autor responsável pela correspondência
Email: kulovnn@mail.ru
Moscow, Russia

Bibliografia

  1. Кулов Н.Н., Очкин А.В. Метод расчета плотности смешанных растворов сильных электролитов // Теорет. основы хим. технологии. 2020. Т. 54. № 6. С. 714.
  2. CRC. Handbook of Chemistry and Physics. 86th Edition. Ed. D.R. Lide. 2005.
  3. Seawater. [Электронный ресурс]// Британская энциклопедия – Режим доступа: //www.britannica.com. – (Дата обращения: 4.02.2022).
  4. Seawater. [Электронный ресурс]// Википедия: свобод. энцикл. – Режим доступа: https://en.wikipedia.org. – (Дата обращения: 11.02.2022).
  5. Nayar Kishor G., Sharqawy Mostafa H., Banchik Leonardo D., Lienhard V., John H. (July 2016). “Thermophysical properties of seawater: A review and new correlations that include pressure dependence”. Desalination. 390: 1–24. Цитиp. пo [4].https://doi.org/10.1016/j.desal.2016.02.024
  6. “Thermophysical properties of seawater”. Department of Mechanical Engineering, Massachusetts Institute of Technology. Retrieved 24 February 2017.

Declaração de direitos autorais © А.В. Очкин, Н.Н. Кулов, 2023

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