Redox potentials of uranium in molten eutectic mixture of lithium, potassium, and cesium chlorides

D. S. Maltsev; V. A. Volkovich; B. D. Vasin

doi:10.1134/S0036029516080115

Redox potentials of uranium in molten eutectic mixture of lithium, potassium, and cesium chlorides

作者: Maltsev D.S.¹, Volkovich V.A.¹, Vasin B.D.¹
隶属关系:
1. Ural Federal University named after the First President of Russia B.N. Yeltsin
期: 卷 2016, 编号 8 (2016)
页面: 729-732
栏目: Article
URL: https://journals.rcsi.science/0036-0295/article/view/170753
DOI: https://doi.org/10.1134/S0036029516080115
ID: 170753

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详细

The behavior of uranium(III) and (IV) ions in the melts based on the eutectic mixture of lithium, potassium, and cesium chlorides has been studied using cyclic voltammetry in the range of 573–1073 K. The red-ox potentials of uranium have been determined and formal standard E_U(III)/U(IV)* red-ox potentials have been calculated.