Electrical properties of the LaLiyCo1 – yO3 – δ (0 ≤ y ≤ 0.10) oxides
- Авторы: Vecherskii S.1, Konopel’ko M.1, Batalov N.1, Antonov B.1, Reznitskikh O.1, Yaroslavtseva T.1
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Учреждения:
- Institute of High-Temperature Electrochemistry
- Выпуск: Том 2017, № 8 (2017)
- Страницы: 664-669
- Раздел: Article
- URL: https://journals.rcsi.science/0036-0295/article/view/171658
- DOI: https://doi.org/10.1134/S0036029517080110
- ID: 171658
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Аннотация
The effect of the Li ion concentration on the phase composition, the electrical conductivity, and the thermoelectric power of the LaLiyCo1–yO3–δ (0 ≤ y ≤ 0.1) oxides synthesized by cocrystallization has been studied. It is found that the region of the perovskite-like solid solution LaLiyCo1–yO3–δ is no higher than y = 0.037. In the temperature range 300–1020 K, lithium alloying leads to an increase in the electrical conductivity and a decrease in the positive thermoelectric power of the single-phase samples compared to LaCoO3–δ. The results are discussed using the density of states model proposed by Senarus Rodriguez and Goodenough for LaCoO3–δ and La1–xSrxCoO3–δ and using the Mott theory of noncrystalline substances.
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S. Vecherskii
Institute of High-Temperature Electrochemistry
Автор, ответственный за переписку.
Email: vecherskii@ihte.uran.ru
Россия, ul. Akademicheskaya 20, Yekaterinburg, 620990
M. Konopel’ko
Institute of High-Temperature Electrochemistry
Email: vecherskii@ihte.uran.ru
Россия, ul. Akademicheskaya 20, Yekaterinburg, 620990
N. Batalov
Institute of High-Temperature Electrochemistry
Email: vecherskii@ihte.uran.ru
Россия, ul. Akademicheskaya 20, Yekaterinburg, 620990
B. Antonov
Institute of High-Temperature Electrochemistry
Email: vecherskii@ihte.uran.ru
Россия, ul. Akademicheskaya 20, Yekaterinburg, 620990
O. Reznitskikh
Institute of High-Temperature Electrochemistry
Email: vecherskii@ihte.uran.ru
Россия, ul. Akademicheskaya 20, Yekaterinburg, 620990
T. Yaroslavtseva
Institute of High-Temperature Electrochemistry
Email: vecherskii@ihte.uran.ru
Россия, ul. Akademicheskaya 20, Yekaterinburg, 620990