Optimization of self-propagating high-temperature synthesis using a halogen fluoride as an igniter for reagents
- Авторы: Gaidar S.1, Karelina M.2, Zhigarev V.3
-
Учреждения:
- Russian State Agrarian University—Timiryazev Agricultural Academy
- Moscow Automobile and Road Construction University
- Central Research Institute of Chemistry and Mechanics
- Выпуск: Том 2016, № 13 (2016)
- Страницы: 1268-1270
- Раздел: Powder Metallurgy Technologies
- URL: https://journals.rcsi.science/0036-0295/article/view/171144
- DOI: https://doi.org/10.1134/S0036029516130048
- ID: 171144
Цитировать
Аннотация
The minimum quantity of the high-activity chemical reagent (HACR) that is required for the initiation of self-propagating high-temperature synthesis (SHS) is determined. The experimental results show that 1–1.3 mg ClF3 (gravity flow from a dosing device), BrF3 on the end of a filling knife, or a few ClF2+ SbF6- crystals are sufficient for the initiation of titanium–boron or titanium–carbon high-energy powder charge compositions. Since the quantity of HACR required for SHS initiation is very small, the chemical method of initiation can be used for the development of a mobile ignition device for estimating the ignition of various SHS charge compositions under laboratory conditions and for application in standard reactors.
Об авторах
S. Gaidar
Russian State Agrarian University—Timiryazev Agricultural Academy
Email: karelinamu@mail.ru
Россия, ul. Timiryazevskaya 49, Moscow, 127550
M. Karelina
Moscow Automobile and Road Construction University
Автор, ответственный за переписку.
Email: karelinamu@mail.ru
Россия, Leningradskii pr. 64, Moscow, 125319
V. Zhigarev
Central Research Institute of Chemistry and Mechanics
Email: karelinamu@mail.ru
Россия, ul. Nagatinskaya 16A, Moscow, 115487