Mechanochemical Synthesis of Intermetallic Compounds in the Gallium–Iridium System
- Autores: Pavlov E.1, Chuprov I.1, Nikulin M.1, Mal’tsev E.1, Pshenichnaya A.1,2, Grigoreva T.3, Pastukhov E.4, Skuratov A.5, Lyakhov N.3
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Afiliações:
- OAO Krasnoyarsk Plant of Nonferrous Metals Named after V. N. Gulidov
- Kirensky Institute of Physics, Federal Research Center, Siberian Branch, Russian Academy of Sciences
- Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch, Russian Academy of Sciences
- Institute of Metallurgy, Ural Branch, Russian Academy of Sciences
- Siberian Federal University
- Edição: Volume 2018, Nº 8 (2018)
- Páginas: 728-732
- Seção: Article
- URL: https://journals.rcsi.science/0036-0295/article/view/172036
- DOI: https://doi.org/10.1134/S0036029518080141
- ID: 172036
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Resumo
The interaction between a solid inert metal (Ir) and an active liquid metal (Ga) during mechanical activation in a high-energy planetary mill is studied by X-ray diffraction and scanning electron microscopy with EDS-apparatus for high-resolution energy dispersive X-ray microanalysis. The influence of mechanical activation conditions on the formation of GaxIry intermetallic compounds and GaxIry/Ir composites and on their solubility in various acids is investigated. Being a surfactant for iridium, gallium propagates along the grain boundaries of polycrystalline iridium particles during mechanical activaiton and, hence, sharply decreases their strength. As a result of strong mechanical deformation during activation, the contact surface area between the solid and liquid metals, where the intermetallic compounds form intensely, increases sharply. As a result of treatment of the products of mechanical activaiton by a mixture of concentrated hydrochloric and nitric acids, iridium (>30%) from passes into an acid solution and forms HxIrCly complex compounds, which can interact with bases to form soluble complex salts.
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Sobre autores
E. Pavlov
OAO Krasnoyarsk Plant of Nonferrous Metals Named after V. N. Gulidov
Autor responsável pela correspondência
Email: E.Pavlov@krastsvetmet.ru
Rússia, Krasnoyarsk, 660027
I. Chuprov
OAO Krasnoyarsk Plant of Nonferrous Metals Named after V. N. Gulidov
Email: grig@solid.nsc.ru
Rússia, Krasnoyarsk, 660027
M. Nikulin
OAO Krasnoyarsk Plant of Nonferrous Metals Named after V. N. Gulidov
Email: grig@solid.nsc.ru
Rússia, Krasnoyarsk, 660027
E. Mal’tsev
OAO Krasnoyarsk Plant of Nonferrous Metals Named after V. N. Gulidov
Email: grig@solid.nsc.ru
Rússia, Krasnoyarsk, 660027
A. Pshenichnaya
OAO Krasnoyarsk Plant of Nonferrous Metals Named after V. N. Gulidov; Kirensky Institute of Physics, Federal Research Center, Siberian Branch, Russian Academy of Sciences
Autor responsável pela correspondência
Email: grig@solid.nsc.ru
Rússia, Krasnoyarsk, 660027; Krasnoyarsk, 660036
T. Grigoreva
Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch, Russian Academy of Sciences
Autor responsável pela correspondência
Email: grig@solid.nsc.ru
Rússia, Novosibirsk, 630128
E. Pastukhov
Institute of Metallurgy, Ural Branch, Russian Academy of Sciences
Email: grig@solid.nsc.ru
Rússia, Yekaterinburg, 620016
A. Skuratov
Siberian Federal University
Email: grig@solid.nsc.ru
Rússia, Krasnoyarsk, 660041
N. Lyakhov
Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch, Russian Academy of Sciences
Email: grig@solid.nsc.ru
Rússia, Novosibirsk, 630128
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