Nucleation and growth of metal nanocrystals during electrocrystallization in melts
- Authors: Isaev V.A.1, Grishenkova O.V.1, Semerikova O.L.1, Kosov A.V.1, Zaykov Y.P.1
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Affiliations:
- Institute of High-Temperature Electrochemistry, Ural Branch
- Issue: Vol 2016, No 8 (2016)
- Pages: 742-745
- Section: Article
- URL: https://journals.rcsi.science/0036-0295/article/view/170772
- DOI: https://doi.org/10.1134/S003602951608005X
- ID: 170772
Cite item
Abstract
The initial stages of electrocrystallization in melts are considered. The nucleation and growth rates of metal nanocrystals during electrodeposition are calculated. The diffusion coefficients in the size space in the Fokker–Planck equation, which describes phase formation, are found. The method of calculating the number of nanoclusters formed on an electrode has been proposed. The concentration dependence of the phase formation under potentiostatic and galvanostatic electrodeposition conditions in melts is considered.
Keywords
About the authors
V. A. Isaev
Institute of High-Temperature Electrochemistry, Ural Branch
Author for correspondence.
Email: v.isaev@ihte.uran.ru
Russian Federation, ul. S. Kovalevskoi 22/ul. Akademicheskaya 20, Yekaterinburg, 620137
O. V. Grishenkova
Institute of High-Temperature Electrochemistry, Ural Branch
Email: v.isaev@ihte.uran.ru
Russian Federation, ul. S. Kovalevskoi 22/ul. Akademicheskaya 20, Yekaterinburg, 620137
O. L. Semerikova
Institute of High-Temperature Electrochemistry, Ural Branch
Email: v.isaev@ihte.uran.ru
Russian Federation, ul. S. Kovalevskoi 22/ul. Akademicheskaya 20, Yekaterinburg, 620137
A. V. Kosov
Institute of High-Temperature Electrochemistry, Ural Branch
Email: v.isaev@ihte.uran.ru
Russian Federation, ul. S. Kovalevskoi 22/ul. Akademicheskaya 20, Yekaterinburg, 620137
Yu. P. Zaykov
Institute of High-Temperature Electrochemistry, Ural Branch
Email: v.isaev@ihte.uran.ru
Russian Federation, ul. S. Kovalevskoi 22/ul. Akademicheskaya 20, Yekaterinburg, 620137