Thermodynamics of the Acid–Base Reactions of N-Methylglycine in Aqueous Solutions of HNO3 and KOH
- 作者: Lytkin A.1, Chernikov V.1, Krutova O.1, Badelin V.2, Krutov P.1
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隶属关系:
- Ivanovo State University of Chemistry and Technology
- Institute of Solution Chemistry. Russian Academy of Sciences
- 期: 卷 92, 编号 11 (2018)
- 页面: 2165-2168
- 栏目: Physical Chemistry of Solutions
- URL: https://journals.rcsi.science/0036-0244/article/view/170197
- DOI: https://doi.org/10.1134/S0036024418110249
- ID: 170197
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详细
Enthalpies are determined calorimetrically for the acid–base reactions of N-methylglycine in aqueous solutions of nitric acid and potassium hydroxide at a temperature of 298.15 K and ionic strengths of 0.25, 0.50, and 0.75 (in the presence of KNO3). Standard thermodynamic characteristics of the acid–base reactions of N-methylglycine are calculated. The effect the concentration of the background electrolyte has on the enthalpy of sarcosine dissociation is considered.
作者简介
A. Lytkin
Ivanovo State University of Chemistry and Technology
Email: kdvkonkpd@yandex.ru
俄罗斯联邦, Ivanovo, 153000
V. Chernikov
Ivanovo State University of Chemistry and Technology
Email: kdvkonkpd@yandex.ru
俄罗斯联邦, Ivanovo, 153000
O. Krutova
Ivanovo State University of Chemistry and Technology
编辑信件的主要联系方式.
Email: kdvkonkpd@yandex.ru
俄罗斯联邦, Ivanovo, 153000
V. Badelin
Institute of Solution Chemistry. Russian Academy of Sciences
Email: kdvkonkpd@yandex.ru
俄罗斯联邦, Ivanovo, 153045
P. Krutov
Ivanovo State University of Chemistry and Technology
Email: kdvkonkpd@yandex.ru
俄罗斯联邦, Ivanovo, 153000