Determining Role of the Chain Mechanism in the Temperature Dependence of the Gas-Phase Rate of Combustion Reactions
- 作者: Azatyan V.1, Bolod’yan I.2, Kopylov N.2, Kopylov S.2, Prokopenko V.1, Shebeko Y.2
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隶属关系:
- Institute of Structural Macrokinetics and Materials Science
- National Research Institute for Fire Protection
- 期: 卷 92, 编号 5 (2018)
- 页面: 847-852
- 栏目: Chemical Kinetics and Catalysis
- URL: https://journals.rcsi.science/0036-0244/article/view/169987
- DOI: https://doi.org/10.1134/S0036024418050047
- ID: 169987
如何引用文章
详细
It is shown that the strong dependence of the rate of gas-phase combustion reactions on temperature is determined by the high values of the reaction rate constants of free atoms and radicals. It is established that with a branched chain mechanism, a special role in the reaction rate temperature dependence is played by positive feedback between the concentrations of active intermediate species and the rate of their change. The role of the chemical mechanism in the temperature dependence of the process rate with and without inhibitors is considered.
作者简介
V. Azatyan
Institute of Structural Macrokinetics and Materials Science
编辑信件的主要联系方式.
Email: azatyan@ism.ac.ru
俄罗斯联邦, Chernogolovka, Moscow oblast, 142432
I. Bolod’yan
National Research Institute for Fire Protection
Email: azatyan@ism.ac.ru
俄罗斯联邦, Balashikha, Moscow oblast, 143903
N. Kopylov
National Research Institute for Fire Protection
Email: azatyan@ism.ac.ru
俄罗斯联邦, Balashikha, Moscow oblast, 143903
S. Kopylov
National Research Institute for Fire Protection
Email: azatyan@ism.ac.ru
俄罗斯联邦, Balashikha, Moscow oblast, 143903
V. Prokopenko
Institute of Structural Macrokinetics and Materials Science
Email: azatyan@ism.ac.ru
俄罗斯联邦, Chernogolovka, Moscow oblast, 142432
Yu. Shebeko
National Research Institute for Fire Protection
Email: azatyan@ism.ac.ru
俄罗斯联邦, Balashikha, Moscow oblast, 143903