Model of multistep electron transfer in a single-mode polar medium
- 作者: Feskov S.1, Yudanov V.2
-
隶属关系:
- Volgograd State University
- Voevodsky Institute of Chemical Kinetics and Combustion, Siberian Branch
- 期: 卷 91, 编号 9 (2017)
- 页面: 1816-1823
- 栏目: Photochemistry and Magnetochemistry
- URL: https://journals.rcsi.science/0036-0244/article/view/169709
- DOI: https://doi.org/10.1134/S0036024417090102
- ID: 169709
如何引用文章
详细
A mathematical model of multistep photoinduced electron transfer (PET) in a polar medium with a single relaxation time (Debye solvent) is developed. The model includes the polarization nonequilibrity formed in the vicinity of the donor–acceptor molecular system at the initial steps of photoreaction and its influence on the subsequent steps of PET. It is established that the results from numerical simulation of transient luminescence spectra of photoexcited donor–acceptor complexes (DAC) conform to calculated data obtained on the basis of the familiar experimental technique used to measure the relaxation function of solvent polarization in the vicinity of DAC in the picosecond and subpicosecond ranges.
作者简介
S. Feskov
Volgograd State University
编辑信件的主要联系方式.
Email: serguei.feskov@volsu.ru
俄罗斯联邦, Volgograd, 400062
V. Yudanov
Voevodsky Institute of Chemical Kinetics and Combustion, Siberian Branch
Email: serguei.feskov@volsu.ru
俄罗斯联邦, Novosibirsk, 630090