Thermodynamic characteristics of the dissolution of glycine, glycylglycine, and glycylglycylglycine in aqueous solutions of sodium dodecyl sulfate at Т = 298.15 K
- 作者: Smirnov V.1, Badelin V.1
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隶属关系:
- Krestov Institute of Solution Chemistry
- 期: 卷 91, 编号 9 (2017)
- 页面: 1681-1684
- 栏目: Physical Chemistry of Solutions
- URL: https://journals.rcsi.science/0036-0244/article/view/169690
- DOI: https://doi.org/10.1134/S0036024417090291
- ID: 169690
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详细
the enthalpies of dissolution of glycine (Gly), glycylglycine (GlyGly), and glycylglycylglycine (GlyGlyGly) are measured in aqueous solutions of sodium dodecyl sulfate (SDS) at SDS concentrations m = 0–0.7 mol kg−1 and Т = 298.15 K by means of calorimetry. The obtained data are used to calculate the standard values of enthalpies of dissolution (ΔsolHm) and enthalpies of transfer (ΔtrHm) of glycine and its oligomers from water to SDS aqueous solutions. The dependences of ΔsolHm and ΔtrHm on SDS concentration in an aqueous solution at a constant concentration of glycine and its oligomers are determined. A comparative analysis of the thermodynamic characteristics of Gly, GlyGly, and GlyGlyGly transfer within the studied range of SDS concentrations is performed. The results are interpreted in terms of ion–ion, ion–polar, and hydrophobic interactions between SDS and molecules of glycine and its oligomers.
作者简介
V. Smirnov
Krestov Institute of Solution Chemistry
编辑信件的主要联系方式.
Email: vis@isc-ras.ru
俄罗斯联邦, Ivanovo, 153045
V. Badelin
Krestov Institute of Solution Chemistry
Email: vis@isc-ras.ru
俄罗斯联邦, Ivanovo, 153045