Thermal and volumetric properties of methanol–hexamethylphosphortriamide mixtures under standard conditions
- 作者: Batov D.1,2, Kustov A.1,2, Antonova O.1,2, Smirnova N.1,2
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隶属关系:
- Krestov Institute of Solution Chemistry
- Ivanovo State University of Chemistry and Technology
- 期: 卷 91, 编号 2 (2017)
- 页面: 323-329
- 栏目: Physical Chemistry of Solutions
- URL: https://journals.rcsi.science/0036-0244/article/view/169269
- DOI: https://doi.org/10.1134/S0036024417020054
- ID: 169269
如何引用文章
详细
Enthalpic and volumetric characteristics of mixing in a methanol (MeOH)–hexamethylphosphortriamide (HMPT, 2) mixture are studied. Based on an analysis of concentration changes in the obtained data and the calculated partial molar characteristics, it is shown that at 0.2 molar fractions > х2 > 0.7 molar fractions, the variation in the composition of the mixture slightly alters the character of intermolecular interactions characteristic of pure components. It is found that MeOH–HMPT mixtures experience most changes in intermolecular interaction and structure within the range of 0.2–0.7 molar fractions of HMPT.
作者简介
D. Batov
Krestov Institute of Solution Chemistry; Ivanovo State University of Chemistry and Technology
编辑信件的主要联系方式.
Email: bat21dv@yandex.ru
俄罗斯联邦, Ivanovo, 153045; Ivanovo, 153000
A. Kustov
Krestov Institute of Solution Chemistry; Ivanovo State University of Chemistry and Technology
Email: bat21dv@yandex.ru
俄罗斯联邦, Ivanovo, 153045; Ivanovo, 153000
O. Antonova
Krestov Institute of Solution Chemistry; Ivanovo State University of Chemistry and Technology
Email: bat21dv@yandex.ru
俄罗斯联邦, Ivanovo, 153045; Ivanovo, 153000
N. Smirnova
Krestov Institute of Solution Chemistry; Ivanovo State University of Chemistry and Technology
Email: bat21dv@yandex.ru
俄罗斯联邦, Ivanovo, 153045; Ivanovo, 153000