Catalytic Activity of Cu and Cu–Fe Hydrosilicates in Hydrogenation with Molecular Hydrogen
- Авторы: Kirichenko O.1,2, Shuvalova E.1, Strekalova A.1,2, Davshan N.1, Kapustin G.1, Nissenbaum V.1
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Учреждения:
- Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
- Moscow State University of Fine Chemical Technologies (MITHT)
- Выпуск: Том 92, № 12 (2018)
- Страницы: 2417-2423
- Раздел: Physical Chemistry of Hybrid Nanomaterials and Multicomponent Systems
- URL: https://journals.rcsi.science/0036-0244/article/view/170243
- DOI: https://doi.org/10.1134/S0036024418120221
- ID: 170243
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Аннотация
Deposited copper hydrosilicates are synthesized using KSKG industrial silica gel. The hydrosilicates are modified with Fe2+ ions. Their catalytic activity and high selectivity in the hydrogenation of dinitrobenzene is shown to yield nitroaniline and phenylenediamine under mild conditions at 170°C and a hydrogen pressure of 1.3 MPa. As an example, C–C triple bond in phenylacetylene is hydrogenated for the first time on such materials using molecular hydrogen under relatively mild conditions.
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Об авторах
O. Kirichenko
Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences; Moscow State University of Fine Chemical Technologies (MITHT)
Автор, ответственный за переписку.
Email: okiriche@ioc.ac.ru
Россия, Moscow, 119991; Moscow, 119571
E. Shuvalova
Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Email: okiriche@ioc.ac.ru
Россия, Moscow, 119991
A. Strekalova
Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences; Moscow State University of Fine Chemical Technologies (MITHT)
Email: okiriche@ioc.ac.ru
Россия, Moscow, 119991; Moscow, 119571
N. Davshan
Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Email: okiriche@ioc.ac.ru
Россия, Moscow, 119991
G. Kapustin
Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Email: okiriche@ioc.ac.ru
Россия, Moscow, 119991
V. Nissenbaum
Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Email: okiriche@ioc.ac.ru
Россия, Moscow, 119991