Thermal Decomposition in Systems of Acid Zn(II), Co(II), and Ni(II) Maleates with the Formation of Metallic Nanoparticles
- Авторы: Yudanova L.1, Logvinenko V.1,2, Korol’kov I.1,2, Ishchenko A.2,3, Rudina N.3
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Учреждения:
- Nikolaev Institute of Inorganic Chemistry, Russian Academy of Sciences, Siberian Branch
- Novosibirsk State University
- Boreskov Institute of Catalysis, Russian Academy of Sciences, Siberian Branch
- Выпуск: Том 92, № 11 (2018)
- Страницы: 2247-2252
- Раздел: Physical Chemistry of Nanoclusters and Nanomaterials
- URL: https://journals.rcsi.science/0036-0244/article/view/170210
- DOI: https://doi.org/10.1134/S003602441811047X
- ID: 170210
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Аннотация
Conditions of synthesis are optimized and XRD and thermoanalytical studies are performed for normal maleate [Zn(H2O)2(C4H2O4)] and acid maleate [Zn(H2O)4(C4H3O4)2], along with acid Co(II)–Zn(II), Ni(II)–Zn(II) maleates. It is shown that when solid solutions thermally decompose in acidic maleate systems, the kinetically less stable component causes the temperature of decomposition of the more stable component to fall. It is established that the solid residue of Zn(II) maleate after heating to 500°C in a He atmosphere is a composite containing Zn oxide whose reduction to metal begins at 675°C. The decomposition of [(Co0.1Zn0.9)(H2O)4(С4H3O4)2] leads to the oozing of metallic cobalt atoms embedded in the channels of the ZnO structure that act as a catalyst for the spontaneous growth of uniform carbon nanotubes on the surface of the composite. After thermal decomposition of the samples in a system of acid Ni(II) maleate–acid Zn(II) maleate, only the bimetallic phase is observed in the composites, and there is no zinc oxide.
Об авторах
L. Yudanova
Nikolaev Institute of Inorganic Chemistry, Russian Academy of Sciences, Siberian Branch
Автор, ответственный за переписку.
Email: judanova@niic.nsc.ru
Россия, Novosibirsk, 630090
V. Logvinenko
Nikolaev Institute of Inorganic Chemistry, Russian Academy of Sciences, Siberian Branch; Novosibirsk State University
Email: judanova@niic.nsc.ru
Россия, Novosibirsk, 630090; Novosibirsk, 630090
I. Korol’kov
Nikolaev Institute of Inorganic Chemistry, Russian Academy of Sciences, Siberian Branch; Novosibirsk State University
Email: judanova@niic.nsc.ru
Россия, Novosibirsk, 630090; Novosibirsk, 630090
A. Ishchenko
Novosibirsk State University; Boreskov Institute of Catalysis, Russian Academy of Sciences, Siberian Branch
Email: judanova@niic.nsc.ru
Россия, Novosibirsk, 630090; Novosibirsk, 630090
N. Rudina
Boreskov Institute of Catalysis, Russian Academy of Sciences, Siberian Branch
Email: judanova@niic.nsc.ru
Россия, Novosibirsk, 630090