Solvation of Piperidine in Nonaqueous Solvents
- Авторы: Volkova M.A.1, Kuz’mina I.A.1, Kuz’mina K.I.1, Belova N.V.1, Sharnin V.A.1
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Учреждения:
- Ivanovo State University of Chemistry and Technology
- Выпуск: Том 92, № 10 (2018)
- Страницы: 2095-2097
- Раздел: Short Communications
- URL: https://journals.rcsi.science/0036-0244/article/view/170183
- DOI: https://doi.org/10.1134/S0036024418100370
- ID: 170183
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Аннотация
The enthalpies of solvation of piperidine (Ppd) in methanol (MeOH), ethanol (EtOH), N,N‑dimethylformamide (DMF), and dimethylsulfoxide (DMSO) are calculated by means of quantum-chemical modeling. The enthalpies of solvation of Ppd in EtOH and DMF are determined calorimetrically. The energies of Ppd solvation in aprotic solvents is found to be generally governed by universal types of interactions between amine and solvent molecules. The energy contributions from both universal and specific types of interactions to the overall enthalpy of Ppd solvation are determined in amphoteric MeOH and EtOH.
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Об авторах
M. Volkova
Ivanovo State University of Chemistry and Technology
Автор, ответственный за переписку.
Email: oxt703@isuct.ru
Россия, Ivanovo, 153000
I. Kuz’mina
Ivanovo State University of Chemistry and Technology
Email: oxt703@isuct.ru
Россия, Ivanovo, 153000
K. Kuz’mina
Ivanovo State University of Chemistry and Technology
Email: oxt703@isuct.ru
Россия, Ivanovo, 153000
N. Belova
Ivanovo State University of Chemistry and Technology
Email: oxt703@isuct.ru
Россия, Ivanovo, 153000
V. Sharnin
Ivanovo State University of Chemistry and Technology
Email: oxt703@isuct.ru
Россия, Ivanovo, 153000
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