Enthalpy of mixing of porous nanocluster polyoxometalates of keplerate-type Mo72Fe30 with polyvinyl alcohol and polyethylene glycol

Аннотация

The interaction between porous spherical nanocluster polyoxometalate and water-soluble nonionic polymers (polyvinyl alcohol and polyethylene glycol) in the compositions of film is studied via calorimetry. The concentration dependences of the enthalpies of these processes are obtained using calculations based on the thermodynamic cycle.