Kinetics and mechanism of N-chloromethylamine decomposition in solutions
- Авторы: Kuznetsov V.1, Vedenyapina M.1,2, Pleshchev M.1, Gashev S.1, Makhova N.1, Vedenyapin A.1,2
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Учреждения:
- Zelinsky Institute of Organic Chemistry
- Moscow Technological Institute
- Выпуск: Том 90, № 3 (2016)
- Страницы: 541-544
- Раздел: Chemical Kinetics and Catalysis
- URL: https://journals.rcsi.science/0036-0244/article/view/167854
- DOI: https://doi.org/10.1134/S0036024416030225
- ID: 167854
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Аннотация
Kinetics of N-chloromethylamine decomposition in an aqueous base medium and chloroform at different temperatures is studied. The decomposition of N-chloromethylamine is found to obey a second order equation in an aqueous base medium at an equimolar ratio of the reagents and a first order equation in chloroform with excess base. The activation energy of N-chloromethylamine decomposition in the both solvents is determined. A mechanism for the reaction is proposed. N-Chloromethylamine is shown to have approximately equal stability in these solvents within the studied temperature range.
Об авторах
V. Kuznetsov
Zelinsky Institute of Organic Chemistry
Email: mvedenyapina@yandex.ru
Россия, Moscow, 119991
M. Vedenyapina
Zelinsky Institute of Organic Chemistry; Moscow Technological Institute
Автор, ответственный за переписку.
Email: mvedenyapina@yandex.ru
Россия, Moscow, 119991; Moscow, 117292
M. Pleshchev
Zelinsky Institute of Organic Chemistry
Email: mvedenyapina@yandex.ru
Россия, Moscow, 119991
S. Gashev
Zelinsky Institute of Organic Chemistry
Email: mvedenyapina@yandex.ru
Россия, Moscow, 119991
N. Makhova
Zelinsky Institute of Organic Chemistry
Email: mvedenyapina@yandex.ru
Россия, Moscow, 119991
A. Vedenyapin
Zelinsky Institute of Organic Chemistry; Moscow Technological Institute
Email: mvedenyapina@yandex.ru
Россия, Moscow, 119991; Moscow, 117292