Thermodynamic characteristics of the adsorption of organic molecules on modified МCM-41 adsorbents
- Autores: Gus’kov V.1, Sukhareva D.1, Salikhova G.1, Karpov S.2, Kudasheva F.1, Roessner F.3, Borodina E.2
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Afiliações:
- Bashkir State University
- Voronezh State University
- Industrial Chemistry II
- Edição: Volume 91, Nº 7 (2017)
- Páginas: 1319-1323
- Seção: Physical Chemistry of Surface Phenomena
- URL: https://journals.rcsi.science/0036-0244/article/view/169622
- DOI: https://doi.org/10.1134/S0036024417070135
- ID: 169622
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Resumo
The adsorption of a number of organic molecules on samples of МCM-41 adsorbent modified with dichloromethylphenylsilane and subsequently treated with sulfuric acid (MDCS) and N-trimethoxysilylpropyl-N,N,N-trimethylammonium chloride (MNM) is studied. Specific retention volumes equal to the Henry constant are determined by means of inverse gas chromatography at infinite dilution. The thermodynamic characteristics of adsorption, the dispersive and specific components of the Helmholtz energy of adsorption, and the increment of the methyl group to the heat of adsorption are calculated. It is shown that the grafting of aminosilane and phenylsilane groups enhances the forces of dispersion and reduces specific interactions. A greater drop in polarity is observed for MDCS than for MNM, due to the stronger polarity of amoinosilane; the enthalpy factor makes the main contribution to the adsorption of organic compounds on the investigated adsorbents. It is found that the MNM sample is capable of the irreversible adsorption of alcohols.
Sobre autores
V. Gus’kov
Bashkir State University
Autor responsável pela correspondência
Email: guscov@mail.ru
Rússia, Ufa, 450074
D. Sukhareva
Bashkir State University
Email: guscov@mail.ru
Rússia, Ufa, 450074
G. Salikhova
Bashkir State University
Email: guscov@mail.ru
Rússia, Ufa, 450074
S. Karpov
Voronezh State University
Email: guscov@mail.ru
Rússia, Voronezh, 394006
F. Kudasheva
Bashkir State University
Email: guscov@mail.ru
Rússia, Ufa, 450074
F. Roessner
Industrial Chemistry II
Email: guscov@mail.ru
Alemanha, Oldenburg, 26129
E. Borodina
Voronezh State University
Email: guscov@mail.ru
Rússia, Voronezh, 394006