Kinetic and thermodynamic parameters of hydrogen release during the heterogeneous catalytic dehydrogenation of cis- and trans-isomers of perhydro-m-terphenyl
- Autores: Kalenchuk A.1,2, Bogorodskii S.3, Bogdan V.1,2
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Afiliações:
- Department of Chemistry
- Zelinsky Institute of Organic Chemistry
- Advanced Laser Technologies Division, Institute of Laser and Information Technologies
- Edição: Volume 90, Nº 10 (2016)
- Páginas: 1921-1924
- Seção: Chemical Kinetics and Catalysis
- URL: https://journals.rcsi.science/0036-0244/article/view/168803
- DOI: https://doi.org/10.1134/S0036024416100162
- ID: 168803
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Resumo
Comparative studies on the temperature dependence of the dehydrogenation of cis- and trans-isomers of perhydro-m-terphenyl are performed in a flow catalytic reactor. Rate constants and equilibrium constants of all elementary acts of this reaction are calculated on basis of experimental data using the KINET 0.8 program for the mathematical modeling of the kinetics of complex reactions. The resulting data indicate that perhydro-m-terphenyl cis- and trans-isomers structural differences have no appreciable effect on dehydrogenation.
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Sobre autores
A. Kalenchuk
Department of Chemistry; Zelinsky Institute of Organic Chemistry
Autor responsável pela correspondência
Email: akalenchuk@yandex.ru
Rússia, Moscow, 119991; Moscow, 119991
S. Bogorodskii
Advanced Laser Technologies Division, Institute of Laser and Information Technologies
Email: akalenchuk@yandex.ru
Rússia, Troitsk, Moscow oblast, 142092
V. Bogdan
Department of Chemistry; Zelinsky Institute of Organic Chemistry
Email: akalenchuk@yandex.ru
Rússia, Moscow, 119991; Moscow, 119991