Theoretical and experimental study of the transformation of 2-pyridone-5-amide into nitrile
- Авторлар: Koval’ Y.1, Okul’ E.1, Yatsenko A.1, Babaev E.1, Polyakova I.2, Rybakov V.1
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Мекемелер:
- Department of Chemistry
- Kurnakov Institute of General and Inorganic Chemistry
- Шығарылым: Том 91, № 2 (2017)
- Беттер: 246-251
- Бөлім: Nanomaterials and Environment
- URL: https://journals.rcsi.science/0036-0244/article/view/169230
- DOI: https://doi.org/10.1134/S0036024417020182
- ID: 169230
Дәйексөз келтіру
Аннотация
Molecular and crystal structures of 2,4-dimethyl-6-oxo-1,6-dihydropyridine-3-carboxamide (1), 2,4-dimethyl-6-oxo-1,6-dihydropyridine-3-carbonitrile (2), and 2-chloro-4,6-dimethylniсotinonitrile (3), which are the products of sequential transformations, are studied by means of single crystal diffraction. The procedure for synthesizing each compound is described. All of the compounds are characterized using IR and 1H NMR spectra. Possible reaction pathways are simulated using the density functional theory (DFT).
Негізгі сөздер
Авторлар туралы
Ya. Koval’
Department of Chemistry
Email: okulem@struct.chem.msu.ru
Ресей, Moscow, 119991
E. Okul’
Department of Chemistry
Хат алмасуға жауапты Автор.
Email: okulem@struct.chem.msu.ru
Ресей, Moscow, 119991
A. Yatsenko
Department of Chemistry
Email: okulem@struct.chem.msu.ru
Ресей, Moscow, 119991
E. Babaev
Department of Chemistry
Email: okulem@struct.chem.msu.ru
Ресей, Moscow, 119991
I. Polyakova
Kurnakov Institute of General and Inorganic Chemistry
Email: okulem@struct.chem.msu.ru
Ресей, Moscow, 117901
V. Rybakov
Department of Chemistry
Email: okulem@struct.chem.msu.ru
Ресей, Moscow, 119991