Thermodynamics of DL-α-aminobutyric acid induced solvation mechanism in aqueous KCl solutions at 288.15–308.15 K

Аннотация

The solubilities of DL-α-aminobutyric acid in KCl solutions of different concentrations are measured at 288.15–308.15 K. Gibbs energies and entropies have been determined for transfer of α-aminobutyric acid form water to aqueous KCl solution at 298.15 K. The cavity, dipole-dipole and other interactions affecting the solubility, as well as stability of the amino acid in solution are also evaluated. Gibbs energy and entropy of transfer due to interactions are computed to create the model of the complex solute-solvent and solventsolvent interactions. Molar volume, densities, dipole moment of solvent and diameter of co-solvent in aqueous potassium chloride are also evaluated.