Liquid–vapor phase equilibria and the thermodynamic properties of 2-methylpropanol–n-alkyl propanoate solutions
- Авторлар: Suntsov Y.1, Goryunov V.1, Chuikov A.1, Meshcheryakov A.1
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Мекемелер:
- Voronezh Institute, State Fire Service
- Шығарылым: Том 90, № 8 (2016)
- Беттер: 1596-1601
- Бөлім: Physical Chemistry of Solutions
- URL: https://journals.rcsi.science/0036-0244/article/view/168598
- DOI: https://doi.org/10.1134/S0036024416080288
- ID: 168598
Дәйексөз келтіру
Аннотация
The boiling points of solutions of five binary systems are measured via ebulliometry in the pressure range of 2.05–103.3 kPa. Equilibrium vapor phase compositions, the values of the excess Gibbs energies, enthalpies, and entropies of solution of these systems are calculated. Patterns in the changes of phase equilibria and thermodynamic properties of solutions are established, depending on the compositions and temperatures of the systems. Liquid–vapor equilibria in the systems are described using the equations of Wilson and the NRTL (Non-Random Two-Liquid Model).
Авторлар туралы
Yu. Suntsov
Voronezh Institute, State Fire Service
Хат алмасуға жауапты Автор.
Email: jsyntsov@mail.ru
Ресей, Voronezh, 394052
V. Goryunov
Voronezh Institute, State Fire Service
Email: jsyntsov@mail.ru
Ресей, Voronezh, 394052
A. Chuikov
Voronezh Institute, State Fire Service
Email: jsyntsov@mail.ru
Ресей, Voronezh, 394052
A. Meshcheryakov
Voronezh Institute, State Fire Service
Email: jsyntsov@mail.ru
Ресей, Voronezh, 394052