Concentration dependences of the physicochemical properties of a water–acetone system
- Authors: Fedyaeva O.A.1, Poshelyuzhnaya E.G.1
-
Affiliations:
- Omsk State Technical University
- Issue: Vol 91, No 1 (2017)
- Pages: 63-66
- Section: Physical Chemistry of Solutions
- URL: https://journals.rcsi.science/0036-0244/article/view/169169
- DOI: https://doi.org/10.1134/S003602441701006X
- ID: 169169
Cite item
Abstract
Concentration dependences of the UV spectrum, refractive index, specific electrical conductivity, boiling point, pH, surface tension, and heats of dissolution of a water–acetone system on the amount of acetone in the water are studied. It is found that the reversible protolytic interaction of the components occurs in all such solutions, resulting in the formation of hydroxyl and acetonium ions. It is shown that shifts of the equilibrium between the molecules and ions in the solution leads to extreme changes in their electrical properties. It is concluded that the formation of acetone solutions of water is accompanied by heat absorption, while the formation of aqueous solutions of acetone is accompanied by heat release.
About the authors
O. A. Fedyaeva
Omsk State Technical University
Author for correspondence.
Email: kosatine@mail.ru
Russian Federation, Omsk, 644050
E. G. Poshelyuzhnaya
Omsk State Technical University
Email: kosatine@mail.ru
Russian Federation, Omsk, 644050