Effect the conditions of the acid–thermal modification of clinoptilolite have on the catalytic properties of palladium–copper complexes anchored on it in the reaction of carbon monoxide oxidation
- Authors: Rakitskaya T.L.1, Kiose T.A.1,2, Ennan A.A.2, Golubchik K.O.1,2, Oleksenko L.P.3, Gerasiova V.G.3
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Affiliations:
- Mechnikov National University
- Physicochemical Institute of the Environment and Human Protection
- Taras Shevchenko National University
- Issue: Vol 90, No 6 (2016)
- Pages: 1120-1127
- Section: Chemical Kinetics and Catalysis
- URL: https://journals.rcsi.science/0036-0244/article/view/168275
- DOI: https://doi.org/10.1134/S0036024416060182
- ID: 168275
Cite item
Abstract
The dependence of the physicochemical and structural–adsorption properties of natural and acid–thermal modified clinoptilolite, and of Pd(II)–Cu(II) catalysts based on them, on the duration of acid–thermal modification is investigated. The samples under study are described via XRD and thermal gravimetric (DTG and DTA) analysis, IR, DR UV–Vis, EPR spectroscopy, and water vapor adsorption. Values of both the specific surface area (Ssp) and pH of aqueous suspensions are determined. The resulting catalysts are tested in the reaction of low-temperature carbon monoxide oxidation with air oxygen. A conclusion is drawn about the nature of surface bimetallic Pd(II)–Cu(II) complexes. The greatest catalytic activity is shown by complexes based on clinoptilolite and modified with 3 M HNO3 for 0.5 and 1 h.
About the authors
T. L. Rakitskaya
Mechnikov National University
Author for correspondence.
Email: tlr@onu.edu.ua
Ukraine, Odessa, 65000
T. A. Kiose
Mechnikov National University; Physicochemical Institute of the Environment and Human Protection
Email: olexludmil@ukr.net
Ukraine, Odessa, 65000; Odessa, 65082
A. A. Ennan
Physicochemical Institute of the Environment and Human Protection
Email: olexludmil@ukr.net
Ukraine, Odessa, 65082
K. O. Golubchik
Mechnikov National University; Physicochemical Institute of the Environment and Human Protection
Email: olexludmil@ukr.net
Ukraine, Odessa, 65000; Odessa, 65082
L. P. Oleksenko
Taras Shevchenko National University
Author for correspondence.
Email: olexludmil@ukr.net
Ukraine, Kyiv, 01601
V. G. Gerasiova
Taras Shevchenko National University
Email: olexludmil@ukr.net
Ukraine, Kyiv, 01601