Mutual cation substitutions in palmierite orthovanadates: M3(VO4)2–M2Me2/3(VO4)2 systems where M = Sr, Ba, or Pb and Me = La or Bi


Дәйексөз келтіру

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Аннотация

We performed the synthesis and studied the extents and compositions of solid solutions (ss) formed by heterovalent substitutions in M3(VO4)2–M2Me2/3(VO4)2 systems where M = Sr, Ba, or Pb and Me = La or Bi. A continuous solid solution (css) series was shown to be formed only when the initial compounds crystallize in palmierite structure. Bi3+ and La3+ were shown to occupy different positions (3а and 6с, respectively) in the crystal lattice of Sr3(VO4)2-base ss.

Авторлар туралы

V. Zhuravlev

Institute of Solid State Chemistry, Ural Branch

Хат алмасуға жауапты Автор.
Email: zhvd@ihim.uran.ru
Ресей, ul. Pervomaiskaya 91, Yekaterinburg, 620990

Yu. Velikodny

Moscow State University

Email: zhvd@ihim.uran.ru
Ресей, Moscow, 119991

A. Tyutyunnik

Institute of Solid State Chemistry, Ural Branch

Email: zhvd@ihim.uran.ru
Ресей, ul. Pervomaiskaya 91, Yekaterinburg, 620990

N. Lobachevskaya

Institute of Solid State Chemistry, Ural Branch

Email: zhvd@ihim.uran.ru
Ресей, ul. Pervomaiskaya 91, Yekaterinburg, 620990

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