电邮这篇文章 Synthesis and thermal dehydration of hexaaquarhodium(III) phosphates
- 作者: Belyaev A.V.1, Kozlova S.G.1, Pishchur D.P.1, Moroz N.K.1, Vorob’eva S.N.1,2
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隶属关系:
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch
- Novosibirsk State University
- 期: 卷 61, 编号 3 (2016)
- 页面: 291-295
- 栏目: Synthesis and Properties of Inorganic Compounds
- URL: https://journals.rcsi.science/0036-0236/article/view/167179
- DOI: https://doi.org/10.1134/S0036023616030050
- ID: 167179
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详细
Complex salts [Rh(H2O)6]PO4 (I) and [Rh(H2O)6]PO4 · H2O (II) were obtained. Dehydration processes of compounds I and II were studied by thermogravimetry and differential scanning calorimetry. The heat effect for the loss of 0.82 ± 0.01 H2O (hydration) molecule was found to be 54 ± 1 kJ/mol, while that for the loss of coordinated H2O is 47 ± 1 kJ/mol (for I) and 43 ± 1 kJ/mol (for II). The solid phases of dehydration products were studied by X-ray powder diffraction, IR and 31P MAS NMR spectroscopy, and they were found to be polymers.
作者简介
A. Belyaev
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
编辑信件的主要联系方式.
Email: abel@niic.nsc.ru
俄罗斯联邦, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090
S. Kozlova
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: abel@niic.nsc.ru
俄罗斯联邦, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090
D. Pishchur
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: abel@niic.nsc.ru
俄罗斯联邦, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090
N. Moroz
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: abel@niic.nsc.ru
俄罗斯联邦, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090
S. Vorob’eva
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk State University
Email: abel@niic.nsc.ru
俄罗斯联邦, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090; ul. Pirogova 2, Novosibirsk, 630090
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