Structure of Monomeric Octahedral d2-Rhenium(V) Monooxo Complexes [ReO(Ltri)(Lbi)] and [ReO(Ltetra)(Lmono)] with Oxygen Atoms of Tridentate (O, O, O) and Tetradentate (O, O, O, O) Chelating Ligands
- Авторы: Sergienko V.S.1,2, Strashnova S.B.3
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Учреждения:
- Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
- All-Russia Institute for Scientific and Technical Information, Russian Academy of Sciences
- Peoples’ Friendship University of Russia
- Выпуск: Том 64, № 7 (2019)
- Страницы: 882-885
- Раздел: Coordination Compounds
- URL: https://journals.rcsi.science/0036-0236/article/view/169414
- DOI: https://doi.org/10.1134/S0036023619070143
- ID: 169414
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Аннотация
The structural features of four mononuclear octahedral d2-Re(V) monooxo complexes [ReO(Ltri)(Lbi)] and [ReO(Ltetra)(Lmono) with tridentate (O, O, O) and tetradentate (O, O, O, O) chelating ligands are discussed. It is shown that the Re–O(Ltri)trans bonds are elongated, whereas the Re–O(Ltetra)trans bonds are shortened as compared to the Re–O(L)cis bonds.
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Об авторах
V. Sergienko
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences; All-Russia Institute for Scientific and Technical Information, Russian Academy of Sciences
Автор, ответственный за переписку.
Email: sergienko@igic.ras.ru
Россия, Moscow, 119991; Moscow, 125190
S. Strashnova
Peoples’ Friendship University of Russia
Email: sergienko@igic.ras.ru
Россия, Moscow, 117198
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